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Biomimetic Chitin-Silk Hybrids: An Optically Transparent Structural Platform for Wearable Devices and Advanced Electronics

机译:仿生甲壳素-丝绸混合体:可穿戴设备和先进电子设备的光学透明结构平台

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摘要

The cuticles of insects and marine crustaceans are fascinating models for man-made advanced functional composites. The excellent mechanical properties of these biological structures rest on the exquisite self-assembly of natural ingredients, such as biominerals, polysaccharides, and proteins. Among them, the two commonly found building blocks in the model biocomposites are chitin nanofibers and silk-like proteins with beta-sheet structure. Despite being wholly organic, the chitinous protein complex plays a key role for the biocomposites by contributing to the overall mechanical robustness and structural integrity. Moreover, the chitinous protein complex alone without biominerals is optically transparent (e.g., dragonfly wings), thereby making it a brilliant model material system for engineering applications where optical transparency is essentially required. Here, inspired by the chitinous protein complex of arthropods cuticles, an optically transparent biomimetic composite that hybridizes chitin nanofibers and silk fibroin (beta-sheet) is introduced, and its potential as a biocompatible structural platform for emerging wearable devices (e.g., smart contact lenses) and advanced displays (e.g., transparent plastic cover window) is demonstrated.
机译:昆虫和海洋甲壳类动物的表皮是人造高级功能复合材料的迷人模型。这些生物结构的出色机械性能取决于天然成分(例如生物矿物质,多糖和蛋白质)的精细自组装。其中,模型生物复合材料中最常见的两个构建基是几丁质纳米纤维和具有β-折叠结构的丝状蛋白。尽管是完全有机的,但几丁质蛋白质复合物通过促进整体机械强度和结构完整性,对生物复合材料起着关键作用。此外,仅不含生物矿物质的几丁质蛋白质复合物是光学透明的(例如,蜻蜓翅膀),因此使其成为在需要光学透明性的工程应用中出色的模型材料系统。在此,受节肢动物表皮的几丁质蛋白质复合物的启发,引入了一种光学透明的仿生复合材料,该复合材料将几丁质纳米纤维和丝素蛋白(β-sheet)杂交,并具有潜在的生物相容性结构平台的作用,可用于新兴的可穿戴设备(例如智能隐形眼镜) ),并演示了高级显示器(例如,透明的塑料盖窗口)。

著录项

  • 来源
    《Advanced Functional Materials》 |2018年第24期|1705480.1-1705480.11|共11页
  • 作者单位

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

    Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Wearable Platform Mat Technol Ctr, 291 Daehak Ro, Daejeon 34141, South Korea;

    UNIST, Sch Mat Sci & Engn, Wearable Elect Res Grp, Ulsan 44919, South Korea;

    UNIST, Sch Mat Sci & Engn, Wearable Elect Res Grp, Ulsan 44919, South Korea;

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

    Korea Electrotech Res Inst, Creat & Fundamental Res Div, 12 Bulmosan Ro,10beon Gil, Chang Won 51543, South Korea;

    UNIST, Sch Mat Sci & Engn, Wearable Elect Res Grp, Ulsan 44919, South Korea;

    Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Wearable Platform Mat Technol Ctr, 291 Daehak Ro, Daejeon 34141, South Korea;

    Univ Ulsan, Sch Mat Sci & Engn, 93 Daehak Ro, Ulsan 44610, South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    chitin; composites; contact lenses; electronics; silk;

    机译:甲壳素;复合材料;隐形眼镜;电子产品;丝绸;

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