Fluorination of Black Phosphorus-Will Black Phosphorus Burn Down in the Elemental Fluorine?

Plutnar Jan; Sturala Jiri; Mazanek Vlastimil; Sofer Zdenek; Pumera Martin

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Fluorination of Black Phosphorus-Will Black Phosphorus Burn Down in the Elemental Fluorine?

机译：黑磷的氟化-黑磷会在元素氟中燃烧掉吗？

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Black phosphorus (BP) represents a promising tunable bandgap alternative to graphene and other 2D materials in the field of semiconductors. However, its reactivity toward covalent modification of its surface (as a key to its bandgap adjustment) is scarcely reported. Here a method of covalent modification of BP involving reaction with fluorine is reported. Other allotropes of phosphorus are known to react violently with fluorine resulting in its complete burning down and formation of gaseous phosphorus pentafluoride. The results of our fluorination experiments conducted in analogy to the procedures used for fluorination of graphene indicate a successful binding of fluorine to BP. This route of modification of BP opens new possible ways toward covalent modification of the surface of this promising material.

机译：黑磷（BP）在半导体领域代表了一种有前途的可调谐带隙替代品，可替代石墨烯和其他2D材料。然而，几乎没有报道其对表面的共价修饰的反应性（作为其带隙调节的关键）。此处报道了涉及与氟反应的BP的共价改性方法。已知磷的其他同素异形体会与氟剧烈反应，导致其完全燃烧并形成气态五氟化磷。我们类似于石墨烯氟化过程的氟化实验结果表明，氟与BP的成功结合。 BP的这种修饰途径为这种有前途的材料表面的共价修饰开辟了新的可能途径。

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来源
《Advanced Functional Materials》 |2018年第35期|1801438.1-1801438.9|共9页
作者
Plutnar Jan; Sturala Jiri; Mazanek Vlastimil; Sofer Zdenek; Pumera Martin;
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作者单位

Univ Chem & Technol Prague, Dept Inorgan Chem, Tech 5, Prague, Czech Republic;

Univ Chem & Technol Prague, Dept Inorgan Chem, Tech 5, Prague, Czech Republic;

Univ Chem & Technol Prague, Dept Inorgan Chem, Tech 5, Prague, Czech Republic;

Univ Chem & Technol Prague, Dept Inorgan Chem, Tech 5, Prague, Czech Republic;

Univ Chem & Technol Prague, Dept Inorgan Chem, Tech 5, Prague, Czech Republic;

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原文格式 PDF
正文语种 eng
中图分类
关键词
black phosphorus; fluorination; fluorine;

机译：黑磷;氟化;氟;

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1. FLUORINATION OF CARBON BLACKS - AN X-RAY PHOTOELECTRON SPECTROSCOPY STUDY .3. FLUORINATION OF DIFFERENT CARBON BLACKS WITH GASEOUS FLUORINE AT TEMPERATURES BELOW 100-DEGREES-C INFLUENCE OF THE MORPHOLOGY, STRUCTURE AND PHYSICO-CHEMICAL CHARACTERISTIC [J] . Nanse G., Fioux P., Moguet F., Carbon: An International Journal Sponsored by the American Carbon Society . 1997,第4期

机译：碳黑的氟化-X射线光电子能谱研究3。在低于100度C的形态，结构和理化特性影响下，用气态氟对不同的碳黑进行氟化
2. FLUORINATION OF CARBON BLACKS - AN X-RAY PHOTOELECTRON SPECTROSCOPY STUDY .2. XPS STUDY OF A FURNACE CARBON BLACK TREATED WITH GASEOUS FLUORINE AT TEMPERATURES BELOW 100-DEGREES-C - INFLUENCE OF THE REACTION PARAMETERS AND OF THE ACTIVATION OF THE CA [J] . Nanse G., Fioux P., Moguet F., Carbon: An International Journal Sponsored by the American Carbon Society . 1997,第3期

机译：碳黑的氟化-X射线光电子能谱研究2。低于100度C的气态氟处理炉膛碳黑的XPS研究-反应参数的影响和CA的活化。
3. In Situ Cleaning and Fluorination of Black Phosphorus for Enhanced Performance of Transistors with High Stability [J] . Hsieh Yu-Ling, Su Wen-Hsuan, Huang Cheng-Chun, ACS applied materials & interfaces . 2020,第33期

机译：原位清洗和黑色磷的氟化，提高具有高稳定性晶体管的性能
4. Gas/liquid microreactors for direct fluorination of aromatic compounds using elemental fluorine [C] . V.Hessel, W.Ehrfeld, Kgt, International conference on microreaction technology . 2000

机译：用于直接氟化芳族化合物的气/液体微反应器使用元素氟
5. Characterizations of fluorine-superconductors and selected fluorine -compounds, vanadium oxydiphosphate by fluorine-19, carbon-13, proton, phosphorus-31 NMR and a new probe for multiple pulse, MAS and DAS NMR. [D] . Pan, Hongjun. 1991

机译：用氟19，碳13，质子，磷31 NMR表征氟超导体和选定的氟化合物，氧合二磷酸钒，并采用多脉冲，MAS和DAS NMR的新探针。
6. Quantum Dots: Fluorination‐Enhanced Ambient Stability and Electronic Tolerance of Black Phosphorus Quantum Dots (Adv. Sci. 9/2018) [O] . Xian Tang, Hong Chen, Joice Sophia Ponraj, 2018

机译：量子点：黑色磷量子点的氟化增强的环境稳定性和电子耐受性（Adv。Sci.9 / 2018）
7. Surface Modification of Acetylene Black with Elemental Fluorine or Nitric Acid and its Application to Oxygen Electrode [O] . Kiyoshi Horita, Yasushi Nishibori 1994

机译：用元素氟或硝酸的乙炔黑表面改性及其在氧气电极的应用
8. Low Temperature Fluorination of Aerosol Suspensions of Hydrocarbons Utilizing Elemental Fluorine. Aerosol Direct Fluorination-Syntheses of Perfluoroketones. [R] . Adcock, J. L., Robin, M. L. 1983

机译：利用元素氟对烃类气溶胶悬浮液进行低温氟化。气溶胶直接氟化 - 全氟酮的合成。

Fluorination of Black Phosphorus-Will Black Phosphorus Burn Down in the Elemental Fluorine?

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