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Advent of 2D Rhenium Disulfide (ReS2): Fundamentals to Applications

机译：二维二硫化R（ReS2）的出现：应用基础

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摘要

Rhenium disulfide (ReS2) is a two-dimensional (2D) group VII transition metal dichalcogenide (TMD). It is attributed with structural and vibrational anisotropy, layer-independent electrical and optical properties, and metal-free magnetism properties. These properties are unusual compared with more widely used group VI-TMDs, e.g., MoS2, MoSe2, WS2 and WSe2. Consequently, it has attracted significant interest in recent years and is now being used for a variety of applications including solid state electronics, catalysis, and, energy harvesting and energy storage. It is anticipated that ReS2 has the potential to be equally used in parallel with isotropic TMDs from group VI for all known applications and beyond. Therefore, a review on ReS2 is very timely. In this first review on ReS2, we critically analyze the available synthesis procedures and their pros/cons, atomic structure and lattice symmetry, crystal structure, and growth mechanisms with an insight into the orientation and architecture of domain and grain boundaries, decoupling of structural and vibrational properties, anisotropic electrical, optical, and magnetic properties impacted by crystal imperfections, doping and adatoms adsorptions, and contemporary applications in different areas.
机译：二硫化hen（ReS2）是二维（2D）的VII族过渡金属二硫化碳（TMD）。其归因于结构和振动各向异性，与层无关的电学和光学特性以及无金属的磁性。与更广泛使用的VI-TMD组（例如MoS2，MoSe2，WS2和WSe2）相比，这些特性是不寻常的。因此，近年来，它引起了极大的兴趣，并且现在被用于各种应用，包括固态电子，催化以及能量收集和能量存储。预计ReS2有潜力与VI组的各向同性TMD并行使用，用于所有已知应用及以后的应用。因此，对ReS2进行审查非常及时。在有关ReS2的第一篇综述中，我们严格分析了可用的合成程序及其优点/缺点，原子结构和晶格对称性，晶体结构以及生长机制，并深入了解了畴和晶界的取向和结构，结构和晶格的解耦。振动性能，各向异性电，光和磁性能受晶体缺陷，掺杂和吸附原子吸附的影响，以及在不同领域的当代应用。

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