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Solution Processed Boron Nitride Nanosheets: Synthesis, Assemblies and Emerging Applications

机译:溶液处理的氮化硼纳米片:合成,组装和新兴应用

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摘要

In the last decade, few-layer boron nitride nanosheets and monolayer BN nanosheet (BNNS) have gained much attention due to their unique physical and chemical properties. To date, BNNS can be produced by micromechanical cleavage of BN crystal, unzipping BN nanotubes, chemical vapor deposition (CVD), and solution processed exfoliation from bulk BN powder. Due to the low cost and abundance of bulk BN powder and its simple processing for potentially scalable production, great efforts have been devoted toward solution processed exfoliation. In this feature article, recent significant advances in solution processed synthesis of BNNS are summarized. In particular, the solvent choice for one-step BN exfoliation is highlighted. Multi-dimensional assemblies consisting of BNNS are discussed, such as BN fiber, BN paper, and BN aerogel. The emerging applications of BNNS in different fields are then focused on, especially in barrier materials, dielectrics, catalysts, and thermal management.
机译:在过去的十年中,几层氮化硼纳米片和单层BN纳米片(BNNS)由于其独特的物理和化学特性而备受关注。迄今为止,BNNS可以通过BN晶体的微机械裂解,BN纳米管解压缩,化学气相沉积(CVD)以及从块状BN粉末进行溶液加工剥离来生产。由于BN散装粉末的价格低廉,数量丰富,并且其简单的加工方法可用于潜在的可扩展生产,因此人们致力于解决溶液剥离的问题。在这篇专题文章中,总结了BNNS的溶液处理合成的最新重大进展。特别要强调的是,一步BN剥离的溶剂选择。讨论了由BNNS组成的多维组件,例如BN纤维,BN纸和BN气凝胶。然后将重点介绍BNNS在不同领域的新兴应用,尤其是在阻隔材料,电介质,催化剂和热管理方面。

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