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Optical Properties of Hybrid Organic-Inorganic Materials and their Applications

机译：有机-无机杂化材料的光学性质及其应用

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摘要

Research on hybrid inorganic-organic materials has experienced an explosive growth since the 1980s, with the expansion of soft inorganic chemistry based processes. Indeed, mild synthetic conditions, low processing temperatures provided by "chimie douce" and the versatility of the colloidal state allow for the mixing of the organic and inorganic components at the nanometer scale in virtually any ratio to produce the so called hybrid materials. Today a high degree of control over both composition and nanostructure of these hybrids can be achieved allowing tunable structure-property relationships. This, in turn, makes it possible to tailor and fine-tune many properties (mechanical, optical, electronic, thermal, chemical.) in very broad ranges, and to design specific multifunctional systems for applications. In particular, the field of "Hybrid-Optics" has been very productive not only scientifically but also in terms of applications. Indeed, numerous optical devices based on hybrids are already in, or very close, to the market. This review describes most of the recent advances performed in this field. Emphasis will be given to luminescent, photochromic, NLO and plasmonic properties. As an outlook we show that the controlled coupling between plasmonics and luminescence is opening a land of opportunities in the field of "Hybrid-Optics".
机译：自1980年代以来，随着基于软无机化学的工艺的扩展，对混合无机-有机材料的研究经历了爆炸性的增长。实际上，温和的合成条件，由“ chimie douce”提供的低加工温度以及胶体状态的多功能性允许有机和无机组分以几乎任何比例在纳米级混合以产生所谓的杂化材料。如今，可以实现对这些杂化物的组成和纳米结构的高度控制，从而实现可调整的结构-特性关系。反过来，这使得可以在很宽的范围内调整和微调许多属性（机械，光学，电子，热，化学等），并可以设计用于应用的特定多功能系统。特别地，“混合光学”领域不仅在科学上而且在应用方面都非常有生产力。实际上，许多基于混合动力的光学设备已经在市场中，或者非常接近市场。这篇评论描述了该领域最新的进展。重点将放在发光，光致变色，NLO和等离子体特性上。作为一种前景，我们表明，等离激元和发光之间的受控耦合为“混合光学”领域打开了一片机遇。

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  • 来源
    《Advanced Functional Materials》 |2016年第36期|6506-6544|共39页
  • 作者

    Parola Stephane; Julian-Lopez Beatriz; Carlos Luis D.; Sanchez Clement;

  • 作者单位

    Univ Lyon 1, Ecole Normale Super Lyon, Lab Chim ENS Lyon, CNRS,UMR 5182, 46 Allee Italie, F-69364 Lyon, France;

    Univ Jaume 1, Inst Adv Mat, Castellon De La Plana 12071, Spain;

    Univ Aveiro, Dept Phys, P-3810193 Aveiro, Portugal|Univ Aveiro, CICECO Aveiro Inst Mat, P-3810193 Aveiro, Portugal;

    Univ Paris 06, Coll France, Lab Chim Matiere Condensee Paris, CMCP,UMR 7574, 11 Pl Marcelin Berthelot, F-75005 Paris, France;

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