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Fabrication of All-Water-Based Self-Repairing Superhydrophobic Coatings Based on UV-Responsive Microcapsules

机译:基于紫外线响应微胶囊的全水基自修复超疏水涂料的制备

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摘要

Superhydrophobic coatings that are also self-healing have drawn much attention in recent years for improved durability in practical applications. Typically, the release of the self-healing agents is triggered by temperature and moisture change. In this study, UV-responsive microcapsules are successfully synthesized by Pickering emulsion polymerization using titania (TiO_2) and silica (SiO_2) nanoparticles as the Pickering agents to fabricate all-water-based self-repairing, superhydrophobic coatings. These coatings are environmentally friendly and can be readily coated on various substrates. Compared to conventional superhydrophobic coatings, these coatings can regenerate superhydrophobicity and self-cleaning ability under UV light, mimicking the outdoor environment, after they are mechanically damaged or contaminated with organics. They can maintain the superhydrophobicity after multiple cycles of accelerated weathering tests.
机译:近年来,具有自我修复作用的超疏水性涂料也因在实际应用中提高耐久性而备受关注。通常,温度和湿度的变化会触发自我修复剂的释放。在这项研究中,通过使用二氧化钛(TiO_2)和二氧化硅(SiO_2)纳米粒子作为Pickering剂的Pickering乳液聚合成功地合成了对紫外线敏感的微胶囊,以制造全水基自修复超疏水涂层。这些涂料对环境友好,可以很容易地涂覆在各种基材上。与传统的超疏水性涂料相比,这些涂料在受到机械损坏或被有机物污染后,可在紫外线下再生超疏水性和自清洁能力,模仿室外环境。在加速老化试验的多个循环后,它们可以保持超疏水性。

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  • 来源
    《Advanced Functional Materials》 |2015年第7期|1035-1041|共7页
  • 作者单位

    Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers Advanced Coatings Research Center of Ministry of Education of China Fudan University Shanghai 200433, China;

    Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers Advanced Coatings Research Center of Ministry of Education of China Fudan University Shanghai 200433, China;

    Department of Materials Science and Engineering University of Pennsylvania 3231 Walnut Street, Philadelphia, PA 19104, USA;

    Department of Materials Science and State Key Laboratory of Molecular Engineering of Polymers Advanced Coatings Research Center of Ministry of Education of China Fudan University Shanghai 200433, China;

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