Polyoxometalate-Modified Sponge-Like Graphene Oxide Monolith with Highn   Proton-Conducting Performance

Liu Yiwei; Liu Shumei; Lai Xuying; Miao Jun; He Danfeng; Li Ning; Luo Fang; Shi Zhan; Liu Shuxia

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Polyoxometalate-Modified Sponge-Like Graphene Oxide Monolith with Highn Proton-Conducting Performance

机译：具有高质子传导性能的多金属氧酸盐改性的海绵状氧化石墨烯整体

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Graphene oxide (GO) contains abundant oxygen-containing functional groups acting as hydrogen bond acceptors for proton conduction on its basal plane. However, the dilemma in realizing bulk in-plane conduction and the metastability at room temperature of GO films both obstruct its application. Polyoxometalate-modified sponge-like GO monolith (PEGO) with 3D cross-linking inner structure, which exhibits unique shrink-expand effect to polar solvent, are synthesized. Owing to the introduction of poly

机译：氧化石墨烯（GO）包含大量的含氧官能团，可作为氢键受体在质子基面上传导质子。然而，GO薄膜实现整体面内导电的困境和室温下的亚稳定性都阻碍了其应用。合成了具有3D交联内部结构的多金属氧酸盐改性的海绵状GO整体料（PEGO），其对极性溶剂表现出独特的收缩-膨胀作用。由于引进了聚

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来源
《Advanced Functional Materials》 |2015年第28期|4480-4485|共6页
作者
Liu Yiwei; Liu Shumei; Lai Xuying; Miao Jun; He Danfeng; Li Ning; Luo Fang; Shi Zhan; Liu Shuxia;
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作者单位

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China.;

NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China.;

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正文语种 eng
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关键词
graphene oxide; monoliths; polyoxometalates; proton transport;

机译：氧化石墨烯;整料;多金属氧酸盐;质子传输;

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Polyoxometalate-Modified Sponge-Like Graphene Oxide Monolith with Highn Proton-Conducting Performance

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