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Long Range Self-Assembly of Polythiophene Breath Figures: Optical and Morphological Characterization

机译:聚噻吩呼吸图的远程自组装:光学和形态表征

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摘要

Large-area, device relevant sized microporous thin films are formed with commercially available polythiophenes by the breath figure technique, a water-assisted micropatterning method, with such semitransparent thin films exhibiting periodicity and uniformity dictated by the length of the polymer side chain. Compared to drop-casted thin films, the microporous thin films exhibit increased crystallinity due to stronger packing of the polymer inside the honeycomb frame.
机译:通过呼吸图形技术,水辅助微图案化方法,用市售的聚噻吩形成与装置有关的大尺寸微孔薄膜,这种半透明薄膜表现出周期性的周期性和均匀性,该周期性和均匀性取决于聚合物侧链的长度。与滴铸薄膜相比,由于聚合物在蜂窝框架内的更牢固的堆积,微孔薄膜表现出更高的结晶度。

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  • 来源
    《Advanced Functional Materials》 |2015年第37期|5902-5909|共8页
  • 作者单位

    SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11790 USA.;

    Brookhaven Natl Lab, Ctr Funct Nanomat, Upton, NY 11793 USA.;

    SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11790 USA.;

    SUNY Stony Brook, Dept Mat Sci & Engn, Stony Brook, NY 11790 USA.;

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