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All-Solution-Processed Indium-Free Transparent Composite Electrodes based on Ag Nanowire and Metal Oxide for Thin-Film Solar Cells

机译:基于Ag纳米线和金属氧化物的全溶液处理无铟透明复合电极,用于薄膜太阳能电池

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摘要

Fully solution-processed Al-doped ZnO/silver nanowire (AgNW)/Al-doped ZnO/ZnO multi-stacked composite electrodes are introduced.as a transparent, conductive window layer for thin-film solar cells. Unlike conventional sol-gel synthetic pathways, a newly developed combustion reaction-based sol-gel chemical approach allows dense and uniform composite electrodes at temperatures as low as 200 ℃. The resulting composite layer exhibits high transmittance (93.4% at 550 nm) and low sheet resistance (11.3 Ω sq~(-1)), which are far superior to those of other solution-processed transparent electrodes and are comparable to their sputtered counterparts. Conductive atomic force microscopy reveals that the multi-stacked metal-oxide layers embedded with the AgNWs enhance the photocarrier collection efficiency by broadening the lateral conduction range. This as-developed composite electrode is successfully applied in Cu(In_(1-x),Ca_x)S_2 (CICS) thin-film solar cells and exhibits a power conversion efficiency of 11.03%. The fully solution-processed indium-free composite films demonstrate not only good performance as transparent electrodes but also the potential for applications in various optoelectronic and photovoltaic devices as a cost-effective and sustainable alternative electrode.
机译:介绍了完全固溶处理的铝掺杂ZnO /银纳米线(AgNW)/铝掺杂ZnO / ZnO多堆叠复合电极,作为薄膜太阳能电池的透明导电窗口层。与传统的溶胶-凝胶合成途径不同,新开发的基于燃烧反应的溶胶-凝胶化学方法可在低至200℃的温度下形成致密且均匀的复合电极。所得复合层具有较高的透射率(在550 nm时为93.4%)和较低的薄层电阻(11.3Ωsq〜(-1)),远优于其他固溶处理的透明电极,与溅射后的透明电极相当。导电原子力显微镜显示,嵌入AgNWs的多层金属氧化物层可通过扩大横向导电范围来提高光电载流子收集效率。研制成功的复合电极成功应用于Cu(In_(1-x),Ca_x)S_2(CICS)薄膜太阳能电池,功率转换效率为11.03%。经过完全溶液处理的无铟复合膜不仅表现出作为透明电极的良好性能,而且还具有作为经济高效且可持续的替代电极在各种光电和光伏设备中应用的潜力。

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  • 来源
    《Advanced Functional Materials》 |2014年第17期|2462-2471|共10页
  • 作者单位

    Department of Materials Science and Engineering Yonsei University 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea;

    Department of Materials Science and Engineering Yonsei University 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea;

    Department of Materials Science and Engineering Yonsei University 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea;

    Advanced Materials Division Korea Research Institute of Chemical Technology 19 Sinseongno Yuseong-gu, Daejeon 305-600, Republic of Korea;

    Department of Materials Science and Engineering Yonsei University 50 Yonsei-ro Seodaemun-gu, Seoul 120-749, Republic of Korea;

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