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A Versatile Approach towards Multifunctional Robust Microcapsules with Tunable, Restorable, and Solvent-Proof Superhydrophobicity for Self-Healing and Self-Cleaning Coatings

机译:具有可调节,可修复和耐溶剂超疏水性的​​多功能健壮微胶囊的多功能方法,用于自修复和自清洁涂层

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摘要

Numerous microencapsulation techniques have been developed to encase various chemicals, for which specific processing parameters are required to address the widely differing features of the encapsulated materials. Micro-encapsulation of reactive agents is a powerful technique that has been extensively applied to self-healing materials. However, the poor solvent compatibility and insufficient thermal stability of microcapsules continue to pose challenges for long-term storage, processing, and service in practical applications. Here, an easily modifiable and highly versatile method is reported for preparing various chemicals filled poly(urea-formaldehyde) microcapsules that exhibit superior tightness against solvents and heat and that possess widely tunable, repetitiously self-restorable, and solvent-proof superhydrophobicity. In addition, the low-cost fabrication of biomimetic multifunctional smart coatings is demonstrated for self-healing anticorrosion and self-cleaning antifouling applications by directly dispersing the superhydrophobic microcapsules into and onto a polymer matrix. The methodology presented in this study should inspire the development of multifunctional intelligent materials for applications in related fields.
机译:已经开发出许多微囊化技术来包封各种化学品,为此需要特定的处理参数来解决囊封材料的广泛不同特征。反应剂的微囊化是一种强大的技术,已广泛应用于自修复材料。然而,不良的溶剂相容性和微胶囊的热稳定性不足继续为在实际应用中的长期存储,加工和服务提出挑战。在此,报道了一种易于修改且用途广泛的方法,用于制备各种化学药品填充的聚(脲甲醛)微胶囊,这些微胶囊对溶剂和热表现出优异的密封性,并具有广泛的可调谐性,可重复自我恢复性和耐溶剂性的超疏水性。此外,通过将超疏水性微胶囊直接分散到聚合物基质中和聚合物基质上,证明了仿生多功能智能涂料的低成本制造可用于自修复防腐蚀和自清洁防污应用。这项研究中提出的方法应启发在相关领域中应用的多功能智能材料的开发。

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  • 来源
    《Advanced Functional Materials》 |2014年第43期|6751-6761|共11页
  • 作者单位

    School of Mechanical and Aerospace Engineering Nanyang Technological University Singapore 639798, Singapore,School of Energy Science and Engineering University of Electronic Science and Technology of China Chengdu 610064, China;

    School of Mechanical and Aerospace Engineering Nanyang Technological University Singapore 639798, Singapore;

    School of Mechanical and Aerospace Engineering Nanyang Technological University Singapore 639798, Singapore;

    School of Energy Science and Engineering University of Electronic Science and Technology of China Chengdu 610064, China;

    School of Mechanical and Aerospace Engineering Nanyang Technological University Singapore 639798, Singapore;

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