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Versatile Graphene-Promoting Photocatalytic Performance of Semiconductors: Basic Principles, Synthesis, Solar Energy Conversion, and Environmental Applications

机译:多功能石墨烯促进半导体的光催化性能:基本原理,合成,太阳能转化和环境应用

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摘要

Graphene-semiconductor nanocomposites, considered as a kind of most promising photocatalysts, have shown remarkable performance and drawn significant attention in the field of photo-driven chemical conversion using solar energy, due to the unique physicochemical properties of graphene. The photocatalytic enhancement of graphene-based nanocomposites is caused by the reduction of the recombination of electron-hole pairs, the extension of the light absorption range, increase of absorption of light intensity, enhancement of surface active sites, and improvement of chemical stability of photocatalysts. Recent progress in the photocatalysis development of graphene-based nanocomposites is highlighted and evaluated, focusing on the mechanism of graphene-enhanced photocatalytic activity, the understanding of electron transport, and the applications of graphene-based photocatalysts on water splitting, degradation or oxidization of organic contaminants, photoreduc-tion of CO_2 into renewable fuels, toxic elimination of heavy metal ions, and antibacterial applications.
机译:石墨烯-半导体纳米复合材料被认为是最有前途的光催化剂,由于其独特的理化性质,在太阳能光驱动化学转化领域中表现出卓越的性能并引起了广泛的关注。石墨烯基纳米复合材料的光催化增强是由于电子-空穴对的复合减少,光吸收范围的扩大,光强度吸收的增加,表面活性位点的增强以及光催化剂化学稳定性的改善引起的。 。着重并评估了石墨烯基纳米复合材料在光催化发展方面的最新进展,重点是石墨烯增强的光催化活性的机理,对电子传输的理解以及石墨烯基光催化剂在水的分解,有机物的降解或氧化中的应用。污染物,将CO_2光还原为可再生燃料,有毒消除重金属离子以及应用抗菌技术。

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  • 来源
    《Advanced Functional Materials》 |2013年第40期|4996-5008|共13页
  • 作者单位

    Key Laboratory of Modern Acoustics MOE, Institute of Acoustics Department of Physics Nanjing University Nanjing 210093, P. R. China,National Laboratory of Solid State Microstructures School of Physics Eco-materials and Renewable Energy Research Center (ERERC) Nanjing University Nanjing 210093, P. R. China;

    Key Laboratory of Modern Acoustics MOE, Institute of Acoustics Department of Physics Nanjing University Nanjing 210093, P. R. China,National Laboratory of Solid State Microstructures School of Physics Eco-materials and Renewable Energy Research Center (ERERC) Nanjing University Nanjing 210093, P. R. China;

    National Laboratory of Solid State Microstructures School of Physics Eco-materials and Renewable Energy Research Center (ERERC) Nanjing University Nanjing 210093, P. R. China;

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