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Dramatic Enhancement of Photoluminescence Quantum Yields for Surface-Engineered Si Nanocrystals within the Solar Spectrum

机译:表面工程硅纳米晶体在太阳光谱内的光致发光量子产率的显着提高

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摘要

Substantial improvements of the absolute photoluminescence quantum yield (QY) for surfactant-free silicon nanocrystals (Si-ncs) by atmospheric pressure microplasma 3-dimensional surface engineering are reported. The effect of surface characteristics on carrier multiplication mechanisms is explored using transient induced absorption and photoluminescence QY. Surface engineering of Si-ncs is demonstrated to lead to more than 120 times increase in the absolute QY (from 0.1% up to 12%) within an important spectral range of the solar emission (2.3-3 eV). The Si-ncs QY is shown to be stable when Si-ncs are stored in ethanol at ambient conditions for three months.
机译:报道了通过大气压微等离子体3维表面工程技术对无表面活性剂的硅纳米晶体(Si-ncs)的绝对光致发光量子产率(QY)的实质性改善。使用瞬态诱导吸收和光致发光QY探索了表面特性对载流子增殖机制的影响。事实证明,Si-ncs的表面工程可以在太阳辐射的重要光谱范围(2.3-3 eV)内使绝对QY值增加120倍以上(从0.1%到12%)。当将Si-ncs在环境条件下在乙醇中存储三个月时,表明Si-ncs QY稳定。

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  • 来源
    《Advanced Functional Materials》 |2013年第48期|6051-6058|共8页
  • 作者单位

    Research Center for Photovoltaics National Institute of Advanced Industrial Science and Technology (AIST) Central 2, Umezono 1-1-1, Tsukuba, 305-8568, Japan;

    Van der Waals-Zeeman Institute Science Park 904, 1098 XH Amsterdam, The Netherlands;

    Nanotechnology & Integrated Bio-Engineering Centre (NIBEC) University of Ulster, UK;

    Van der Waals-Zeeman Institute Science Park 904, 1098 XH Amsterdam, The Netherlands,Department of Chemistry, Columbia University, NewYork, NY 10027, USA;

    Van der Waals-Zeeman Institute Science Park 904, 1098 XH Amsterdam, The Netherlands;

    Nanotechnology & Integrated Bio-Engineering Centre (NIBEC) University of Ulster, UK;

    Van der Waals-Zeeman Institute Science Park 904, 1098 XH Amsterdam, The Netherlands;

    Research Center for Photovoltaics National Institute of Advanced Industrial Science and Technology (AIST) Central 2, Umezono 1-1-1, Tsukuba, 305-8568, Japan;

    Research Center for Photovoltaics National Institute of Advanced Industrial Science and Technology (AIST) Central 2, Umezono 1-1-1, Tsukuba, 305-8568, Japan;

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