Rapid Combinatorial Synthesis and Chromatography Based Screening of Phosphorescent Iridium Complexes for Solution Processing

Andreas Hohenleutner; Susanna Schmidbauer; Rudolf Vasold; Dominik Joosten; Philipp Stoessel; Herwig Buchholz; Burkhard Koenig

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Rapid Combinatorial Synthesis and Chromatography Based Screening of Phosphorescent Iridium Complexes for Solution Processing

机译：快速组合合成和色谱法筛选用于溶液处理的磷光铱配合物

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This work reports the combinatorial synthesis and screening of phosphorescent iridium complexes as solution processable emitters for OLEDs. The approach taken here allows for the rapid synthesis, isolation, spectroscopic characterization and identification of the libraries based on chromatographic methods. Subsequent analysis of the irradiation induced degradation provides insight on the stability of the complexes under continuous excitation. The method is versatile and can easily be applied to other metal complexes or organic dyes for various applications, e.g., in electroluminescence, photo-voltaics and sensing.

机译：这项工作报告了磷光铱配合物的组合合成和筛选，可作为OLED的溶液可处理发射体。此处采用的方法可基于色谱方法对文库进行快速合成，分离，光谱表征和鉴定。随后的辐照诱导降解分析提供了在连续激发下复合物稳定性的见解。该方法是通用的，并且可以容易地应用于其他金属配合物或有机染料以用于各种应用，例如在电致发光，光电和感测中。

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来源
《Advanced Functional Materials》 |2012年第16期|p.3406-3413|共8页
作者
Andreas Hohenleutner; Susanna Schmidbauer; Rudolf Vasold; Dominik Joosten; Philipp Stoessel; Herwig Buchholz; Burkhard Koenig;
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Institut fuer Organische Chemie Universitaet Regensburg Universitaetsstraeee 31, D-93053 Regensburg, Germany;

Institut fuer Organische Chemie Universitaet Regensburg Universitaetsstraeee 31, D-93053 Regensburg, Germany;

Institut fuer Organische Chemie Universitaet Regensburg Universitaetsstraeee 31, D-93053 Regensburg, Germany;

Merck KGaA, Performance Materials Division Location F61/383, Frankfurter Str. 250, D-64293 Darmstadt, Germany;

Merck KGaA, Performance Materials Division Location F61/383, Frankfurter Str. 250, D-64293 Darmstadt, Germany;

Merck KGaA, Performance Materials Division Location F61/383, Frankfurter Str. 250, D-64293 Darmstadt, Germany;

Institut fuer Organische Chemie Universitaet Regensburg Universitaetsstraeee 31, D-93053 Regensburg, Germany;

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Rapid Combinatorial Synthesis and Chromatography Based Screening of Phosphorescent Iridium Complexes for Solution Processing

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