• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Advanced Functional Materials >Rapid Room-Temperature Synthesis of Metal-Organic Framework HKUST-1 Crystals in Bulk and as Oriented and Patterned Thin Films
【24h】

Rapid Room-Temperature Synthesis of Metal-Organic Framework HKUST-1 Crystals in Bulk and as Oriented and Patterned Thin Films

机译：金属-有机骨架HKUST-1晶体的大室温取向和图案化薄膜的室温快速合成

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Whereas the preparation of defined metal-organic framework (MOF) materials via hydrothermal or diffusion methods typically requires hours to days, our simple precipitation route opens the access to the well-known HKUST-1 frameworks within minutes. Crucial for the formation of a well-defined, crystalline material is the choice of suitable precipitating solvents, with methanol and ethanol being the most favorable ones. This approach could be extended to the formation of dense, surface-mounted MOF films (so-called SURMOFs), in particular if the surfaces are decorated with suitable binding groups by formation of self-assembled monolayers (SAMs). By combination with micro-contact printing (U.CP), patterned SURMOFs became accessible, in which the precipitating solvent is decisive on the formation of either spatially restricted films or single particles.
机译：通过水热法或扩散法制备确定的金属有机骨架（MOF）材料通常需要数小时至数天，而我们简单的沉淀途径使在几分钟之内即可使用著名的HKUST-1骨架。选择合适的沉淀溶剂对于形成定义明确的结晶材料至关重要，甲醇和乙醇是最优选的沉淀溶剂。该方法可以扩展到形成致密的，表面安装的MOF膜（所谓的SURMOF），特别是如果通过形成自组装单层（SAM）用合适的结合基团装饰表面的话。通过与微接触印刷（U.CP）结合使用，可以使用图案化的SURMOF，其中沉淀溶剂对于形成空间受限的薄膜或单个颗粒起决定性作用。

著录项

  • 来源
    《Advanced Functional Materials》 |2011年第8期|p.1442-1447|共6页
  • 作者

    Jin-Liang Zhuang; Doris Ceglarek; Sangeetha Pethuraj; Andreas Terfort;

  • 作者单位

    Institute for Inorganic and Analytical Chemistry University of Frankfurt Frankfurt, 60325, Germany;

    Institute for Inorganic and Analytical Chemistry University of Frankfurt Frankfurt, 60325, Germany;

    Institute for Inorganic and Analytical Chemistry University of Frankfurt Frankfurt, 60325, Germany;

    Institute for Inorganic and Analytical Chemistry University of Frankfurt Frankfurt, 60325, Germany;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号