Luminescent Tags on Fullerenes: Eu~(3+) Complexes with Pendant Fullerenes

Anita Fuchsbauer; Olesya A. Troshina; Pavel A. Troshin; Robert Koeppe; Rimma N. Lyubovskaya; Niyazi Serdar Sariciftci

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Luminescent Tags on Fullerenes: Eu~(3+) Complexes with Pendant Fullerenes

机译：富勒烯上的发光标记：垂饰富勒烯的Eu〜（3+）配合物

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Novel fullerene-containing Eu (III) complexes are obtained by mixing a fullerene derivative bearing chelating pyridinyl groups with an Eu (III) complex possessing three coordinated 4,4,4,-trifluoro-1-(2-naphtyl)-1,3-butanedione residues and two water molecules. One of the complexes designed is formed in water using a water-soluble fullerene derivative as a precursor material. We investigate the photophysical properties of this new type of highly soluble self-assembled fullerene-derivative Eu~(3+) coordination compounds. A strong emission line of the Eu~(3+) 4f-4f transition is recorded under excitation with UV irradiation. The behaviour of the complexes in organic matrices and water is studied as the first steps towards luminescence tagged fullerene derivatives for use in biomedicine and optoelectronics.

机译：通过将带有螯合吡啶基的富勒烯衍生物与具有三个配位的4,4,4，-三氟-1-（2-萘基）-1,3的Eu（III）配合物混合，可获得新型的含富勒烯的Eu（III）配合物。 -丁二酮残基和两个水分子。设计的配合物之一是使用水溶性富勒烯衍生物作为前体材料在水中形成的。我们研究了这种新型的高可溶性自组装富勒烯衍生物Eu〜（3+）配位化合物的光物理性质。在紫外线照射下，记录到Eu〜（3+）4f-4f跃迁的强发射线。作为在生物医学和光电领域中使用的发光标记富勒烯衍生物的第一步，研究了有机基体和水中络合物的行为。

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《Advanced Functional Materials》 |2008年第18期|p.2808-2814|共7页
作者
Anita Fuchsbauer; Olesya A. Troshina; Pavel A. Troshin; Robert Koeppe; Rimma N. Lyubovskaya; Niyazi Serdar Sariciftci;
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Linz Insitute for Organic Solar Cells (LIOS), Physical Chemistry Johannes Kepler University Linz Altenbergerstrafsse 69, 4040 Linz (Austria);

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中图分类无线电电子学、电信技术;
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1. Template synthesis,Crystal Structure and Luminescent Properties of Neutral N_4O_3 Tripodal Ln~(III)L Complexes (Ln~(III)=La~(3+),Eu~(3+),Gd~(3+),Tb~(3+),Dy~(3+),Ho~(3+),Er~(3+),Tm~(3+) or Lu~(3+);H_3L=Tris{[3'-(2"-pyridyl)-5'-tert-butyl-2'-hydroxyben [J] . Wai-Kwok Wong, Hongze Liang, Jianping Guo, European journal of inorganic chemistry . 2004,第4期

机译：中性N_4O_3三脚架Ln〜（III）L配合物（Ln〜（III）= La〜（3 +），Eu〜（3 +），Gd〜（3 +），Tb〜（ 3 +），Dy〜（3 +），Ho〜（3 +），Er〜（3 +），Tm〜（3+）或Lu〜（3 +）; H_3L = Tris {[3'-（2“ -吡啶基）-5'-叔丁基-2'-羟基苯
2. Supramolecular inclusion complexes of fullerenes using cyclotriveratrylene derivatives with aromatic pendants [J] . Matsubara H., Shiwaku K., Asano K., Chemistry Letters . 1998,第9期

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3. Eu~(3+) Ion as Luminescent Probe:Eu~(3+) Sites in Eu(PBI)_3•phen and [Eu(PBI)_3 • C_2H_5OH • H_2O] • H_2O Complexes [J] . Jin Linpei, Huang Chunhui, Xu Lianbin, Journal of rare earths . 1995,第3期

机译：Eu〜（3+）离子作为发光探针：Eu（PBI）_3•phen和[Eu（PBI）_3•C_2H_5OH•H_2O]•H_2O配合物中的Eu〜（3+）位点
4. Chapter 1 Endohedral Fullerene Complexes. Which and How Many Small Molecules Can Be Inserted into Fullerenes and a Carbon Nanotube? [C] . Helena Dodziuk FP7 International Summer School "Nanotechnology: From Fundamental Research to Innovations" . 2015

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机译：第一部分：细胞色素c氧化酶活性位点建模：新的不对称三（咪唑和吡啶附加）栅栏卟啉及其金属配合物的合成与表征。第二部分迈向基于富勒烯的放射性药物：内含165金属富勒烯的高产中子活化。
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7. Fullerene-driven encapsulation of a luminescent Eu(III) complex in carbon nanotubes [O] . Maggini, Laura, Fuestoes, Melinda-Emese, Chamberlain, Thomas W., 2014

机译：富勒烯驱动的碳纳米管中发光Eu（III）配合物的包封

Luminescent Tags on Fullerenes: Eu~(3+) Complexes with Pendant Fullerenes

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