Self-Assembly of Amphiphilic Calix[4]arenes in Aqueous Solution

Michael Strobel; Katarzyna Kita-Tokarczyk; Andreas Taubert; Corinne Vebert; Paul A. Heiney; Mohamed Chami; Wolfgang Meier

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Self-Assembly of Amphiphilic Calix[4]arenes in Aqueous Solution

机译：两性杯[4]芳烃在水溶液中的自组装

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The self-assembly of amphiphilic calix[4]arenes with either a carboxylic acid or a trimethyl ammonium head group and different alkyl chains in aqueous solution was investigated. The carboxylated calixarene forms vesicles in dilute solution and stable monolayers on water. In contrast, the ammonium head group provides high water solubility with no observed aggregation. At high concentrations, all calixarene amphiphiles form lyotropic liquid crystals.

机译：研究了两亲杯[4]芳烃在水溶液中具有羧酸或三甲基铵首基和不同烷基链的自组装。羧化杯芳烃在稀溶液中形成囊泡，并在水上形成稳定的单层。相反，铵头基团提供高水溶性，没有观察到聚集。在高浓度下，所有杯芳烃两亲物均形成溶致液晶。

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《Advanced Functional Materials》 |2006年第2期|p.252-259|共8页
作者
Michael Strobel; Katarzyna Kita-Tokarczyk; Andreas Taubert; Corinne Vebert; Paul A. Heiney; Mohamed Chami; Wolfgang Meier;
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作者单位

Department of Chemistry, Biozentrum, University of Basel CH-4056 Basel (Switzerland);

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正文语种 eng
中图分类无线电电子学、电信技术;
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Self-Assembly of Amphiphilic Calix[4]arenes in Aqueous Solution

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