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Micro-Raman Scattering Imaging of Langmuir-Blodgett Surface Relife Gratings

机译:Langmuir-Blodgett表面重生光栅的微拉曼散射成像

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摘要

Surface relief gratings (SRGs) recorded on Langmuir-Blodgett (LB) films of an azobenzene homopolymer were visualized using micro-Raman imaging. Raman scattering (RS) was achieved using the 780 nm laser line while pre-resonance Raman scat- tering (pre-RRS) and resonance Raman scattering were achieved using the 633 and 514.5 nm laser lines, respectively. Pre-sur- face-enhanced resonance Raman scattering (pre-SERRS) and surface-enhanced resonance Raman scattering (SERRS) were collected for the LB films covered with a 6 nm thick silver island film. The SRG could be chemically identified by the spatial variation in the Raman signal scattered by the film due to a concentration gradient. The pre-SERRS provided signals of the same intensity along and across the grooves, indicating that the molecular architecture at the SRG surface is the same at the peaks as in the valleys.
机译:记录在偶氮苯均聚物的Langmuir-Blodgett(LB)膜上的表面起伏光栅(SRG)使用显微拉曼成像技术可视化。拉曼散射(RS)使用780 nm激光线实现,而预共振拉曼散射(pre-RRS)和共振拉曼散射分别使用633和514.5 nm激光线实现。对于覆盖有6 nm厚银岛膜的LB膜,收集了表面增强的共振拉曼散射(pre-SERRS)和表面增强的共振拉曼散射(SERRS)。 SRG可以通过浓度梯度导致薄膜散射的拉曼信号的空间变化来化学识别。 SER前沿槽和跨槽提供的信号强度相同,这表明SRG表面的分子结构在峰处与谷处相同。

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