Infrared Spectra of [Ni(dddt)_2]_3(AuBr_2)_2 and [Pd(dddt)_2]_2X (X≡TeCl_6, SbF_6, AuBr_2) Crystals

A. Lapinski; R. Swietlik; L. A. Kushch

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Infrared Spectra of [Ni(dddt)_2]_3(AuBr_2)_2 and [Pd(dddt)_2]_2X (X≡TeCl_6, SbF_6, AuBr_2) Crystals

机译：[Ni（dddt）_2] _3（AuBr_2）_2和[Pd（dddt）_2] _2X（X≡TeCl_6，SbF_6，AuBr_2）晶体的红外光谱

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Polarised reflectance and/or transmission spectra of [Ni(dddt)_2]_3(AuBr_2)_2 and [Pd(dddt)_2]_2X (X≡TeCl_6, SbF_6, AuBr_2; dddt≡5,6-dihydro-1,3-dithiin-2,3-dithiolate) single crystals are measured in the IR region (650-6 500 cm~(-1)). A metal-insulator phase transition in [Pd(dddt)_2]_2SbF_6 at T = 200 K has an influence on the IR spectra. A plasma-edge-like dispersion is analysed in terms of the Drude-Lorentz model. Vibrational and electronic bands are discussed.

机译：[Ni（dddt）_2] _3（AuBr_2）_2和[Pd（dddt）_2] _2X（X≡TeCl_6，SbF_6，AuBr_2;dddt≡5,6-dihydro-1,3-的偏振反射率和/或透射光谱在IR区域（650-6 500 cm〜（-1））中测量了Dithiin-2,3-dithiolate）单晶。 T = 200 K时[Pd（dddt）_2] _2SbF_6中的金属-绝缘体相变对IR光谱有影响。根据Drude-Lorentz模型分析了类似等离子体边缘的分散体。讨论了振动带和电子带。

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来源
《Advanced Materials for Optics and Electronics》 |1996年第6期|p.321-324|共4页
作者
A. Lapinski; R. Swietlik; L. A. Kushch;
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作者单位

Institute of Molecular Physics, Polish Academy of Sciences, Smoluchowskiego 17, 60-179 Poznan, Poland;

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正文语种 eng
中图分类无线电电子学、电信技术;
关键词
Ni(dddt)_2_3(AuBr_2)_2; Pd(dddt)_2_2TeCl_6; Pd(dddt)_2_2SbF_6 and Pd(dddt)_2_2AuBr_2 salts; IR spectra; phase transition; drude-lorentz model;

机译：[Ni（dddt）_2] _3（AuBr_2）_2;[Pd（dddt）_2] _2TeCl_6;[Pd（dddt）_2] _2SbF_6和[Pd（dddt）_2] _2AuBr_2盐;红外光谱;相变;德鲁洛伦茨模型;

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Infrared Spectra of [Ni(dddt)_2]_3(AuBr_2)_2 and [Pd(dddt)_2]_2X (X≡TeCl_6, SbF_6, AuBr_2) Crystals

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