The Rise of Hydrogen Peroxide as the Main Product by Metal-Free Catalysis in Oxygen Reductions

Melchionna Michele; Fornasiero Paolo; Prato Maurizio

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The Rise of Hydrogen Peroxide as the Main Product by Metal-Free Catalysis in Oxygen Reductions

机译：无金属催化氧还原中主要产物过氧化氢的增加

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One of the recent trends in electrocatalytic reactions involves the oxygen reduction reaction (ORR), where a new paradigm has been shaped to exploit this reaction for the synthesis of hydrogen peroxide (H2O2). H2O2 is a very versatile chemical of high commercial value, prepared currently through poorly sustainable processes. The emergence of metal-free carbon catalysts for the selective synthesis of H2O2 is expected to revolutionize ORR research, beckoning at the development of new industrial schemes. The complexities of the mechanism and the factors dominating the selectivity of the process have been unveiled through a combination of theoretical and experimental studies.

机译：电催化反应的最新趋势之一是氧还原反应（ORR），在该反应中已形成了新的范式以利用该反应来合成过氧化氢（H2O2）。 H2O2是一种非常通用的化学品，具有很高的商业价值，目前通过可持续性差的过程制备。选择性地合成H2O2的无金属碳催化剂的出现，有望掀起ORR研究的革命，并吸引着新的工业计划的发展。通过理论和实验研究相结合，揭示了机理的复杂性和决定工艺选择性的因素。

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来源
《Advanced Materials》 |2019年第13期|1802920.1-1802920.5|共5页
作者
Melchionna Michele; Fornasiero Paolo; Prato Maurizio;
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作者单位

Univ Trieste, INSTM, Dept Chem & Pharmaceut Sci, Via L Giorgieri 1, I-34127 Trieste, Italy;

Univ Trieste, INSTM, Dept Chem & Pharmaceut Sci, Via L Giorgieri 1, I-34127 Trieste, Italy|Univ Trieste, ICCOM CNR, Via L Giorgieri 1, I-34127 Trieste, Italy;

Univ Trieste, INSTM, Dept Chem & Pharmaceut Sci, Via L Giorgieri 1, I-34127 Trieste, Italy|CIC biomaGUNE, Carbon Nanobiotechnol Lab, Paseo Miramon 182, Donostia San Sebastian 20009, Spain|Ikerbasque, Basque Fdn Sci, Bilbao 48013, Spain;

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正文语种 eng
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关键词
carbon nanoforms; hydrogen peroxide; metal-free catalysis; oxygen reduction reaction;

机译：碳纳米形式;过氧化氢;无金属催化;氧还原反应;

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1. Efficient hydrogen peroxide synthesis by metal-free polyterthiophene via photoelectrocatalytic dioxygen reduction [J] . Fan Wenjun, Zhang Bingqing, Wang Xiaoyu, Energy & environmental science . 2020,第1期

机译：光电催化双氧还原无金属聚噻吩高效合成过氧化氢
2. A review of advanced metal-free carbon catalysts for oxygen reduction reactions towards the selective generation of hydrogen peroxide [J] . Zhou Yue, Chen Ge, Zhang Jiujun Journal of Materials Chemistry, A. Materials for energy and sustainability . 2020,第40期

机译：对氧还原反应的先进金属碳催化剂对选择性产生的过氧化氢的综述
3. Dual metal-free polymer reactive sites for the efficient degradation of diclofenac by visible light-driven oxygen reduction to superoxide radical and hydrogen peroxide [J] . Zhang Qianxin, Tan Cuiwen, Zheng Xiaoshan, Environmental Science: Nano . 2019,第8期

机译：双金属的聚合物反应性位点，通过可见光氧还原到超氧化物和过氧化氢的可见光氧气的高效降解
4. Conductivity versus Active Sites in Metal-free Oxygen Reduction Reaction Electrocatalysis [C] . Mo Qiao, Cheng Tang, Guanjie He World Conference on Carbon . 2016

机译：导电性与无金属氧还原反应电常分的活性位点
5. Catalyzing Electrochemical Oxygen Reduction to Form Hydrogen Peroxide: From Catalyst Development to Device Integration [D] . Chen, Zhihua. 2019

机译：催化电化学氧还原形成过氧化氢：从催化剂发育到装置整合
6. 3D graphene preparation via covalent amide functionalization for efficient metal-free electrocatalysis in oxygen reduction [O] . Mohammad Shamsuddin Ahmed, Young-Bae Kim -1

机译：通过共价酰胺官能团制备3D石墨烯可在氧还原中进行高效的无金属电催化
7. Dual function photocatalysis of cyano-bridged heteronuclear metal complexes for water oxidation and two-electron reduction of dioxygen to produce hydrogen peroxide as a solar fuel [O] . Yusuke Aratani, Tomoyoshi Suenobu, Kei Ohkubo, 2017

机译：用于水氧化的氰基外核金属配合物的双函数光催化，二氧化根部的二氧化硅减少以生产过氧化氢作为太阳能燃料
8. Electrocatalysis of Oxygen Reduction. Part III. Selective Reduction to Hydrogen Peroxide or Water Using Polymeric Attachment of Metalloporphyrins [R] . Bettelheim, A., Chan, R. J. H., Kuwana, T. 1979

机译：氧还原的电催化。第三部分。使用金属卟啉的聚合物连接选择性还原为过氧化氢或水

The Rise of Hydrogen Peroxide as the Main Product by Metal-Free Catalysis in Oxygen Reductions

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