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A General Approach for Lab-to-Manufacturing Translation on Flexible Organic Solar Cells

机译:柔性有机太阳能电池实验室到制造转换的通用方法

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摘要

The blossoming of organic solar cells (OSCs) has triggered enormous commercial applications, due to their high-efficiency, light weight, and flexibility. However, the lab-to-manufacturing translation of the praisable performance from lab-scale devices to industrial-scale modules is still the Achilles' heel of OSCs. In fact, it is urgent to explore the mechanism of morphological evolution in the bulk heterojunction (BHJ) with different coating/printing methods. Here, a general approach to upscale flexible organic photovoltaics to module scale without obvious efficiency loss is demonstrated. The shear impulse during the coating/printing process is first applied to control the morphology evolution of the BHJ layer for both fullerene and nonfullerene acceptor systems. A quantitative transformation factor of shear impulse between slot-die printing and spin-coating is detected. Compelling results of morphological evolution, molecular stacking, and coarse-grained molecular simulation verify the validity of the impulse translation. Accordingly, the efficiency of flexible devices via slot-die printing achieves 9.10% for PTB7-Th:PC71BM and 9.77% for PBDB-T:ITIC based on 1.04 cm(2) . Furthermore, 15 cm(2) flexible modules with effective efficiency up to 7.58% (PTB7-Th:PC71BM) and 8.90% (PBDB-T:ITIC) are demonstrated with satisfying mechanical flexibility and operating stability. More importantly, this work outlines the shear impulse translation for organic printing electronics.
机译:有机太阳能电池(OSC)的蓬勃发展因其高效,轻巧和灵活而引起了巨大的商业应用。然而,从实验室规模的设备到工业规模的模块,从实验室到生产的可转换性能仍然是OSC的致命弱点。实际上,迫切需要探索采用不同涂层/印刷方法的本体异质结(BHJ)的形态演化机理。在此,展示了一种在不明显降低效率的情况下将柔性有机光伏光伏组件升级至模块规模的通用方法。首先在涂布/印刷过程中施加剪切脉冲,以控制富勒烯和非富勒烯受体系统的BHJ层的形貌演变。检测了狭缝模版印刷和旋涂之间的剪切脉冲的定量转换因子。令人信服的形态演化,分子堆积和粗粒分子模拟结果证明了脉冲翻译的有效性。因此,基于1.04 cm(2),通过狭缝模版印刷的柔性设备的效率对于PTB7-Th:PC71BM达到9.10%,对于PBDB-T:ITIC达到9.77%。此外,还展示了有效效率高达7.58%(PTB7-Th:PC71BM)和8.90%(PBDB-T:ITIC)的15 cm(2)柔性模块,具有令人满意的机械柔韧性和操作稳定性。更重要的是,这项工作概述了有机印刷电子产品的剪切脉冲平移。

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