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Crafting Semiconductor Organic-Inorganic Nanocomposites via Placing Conjugated Polymers in Intimate Contact with Nanocrystals for Hybrid Solar Cells

机译:通过放置共轭聚合物与纳米晶体紧密接触的混合太阳能电池来制作半导体有机-无机纳米复合材料。

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摘要

Semiconductor organic-inorganic hybrid solar cells incorporating conjugated polymers (CPs) and nanocrystals (NCs) offer the potential to deliver efficient energy conversion with low-cost fabrication. The CP-based photovoltaic devices are complimented by an extensive set of advantageous characteristics from CPs and NCs, such as lightweight, flexibility, and solution-processability of CPs, combined with high electron mobility and size-dependent optical properties of NCs. Recent research has witnessed rapid advances in an emerging field of directly tethering CPs on the NC surface to yield an intimately contacted CP-NC nanocomposite possessing a well-defined interface that markedly promotes the dispersion of NCs within the CP matrix, facilitates the photoinduced charge transfer between these two semiconductor components, and provides an effective platform for studying the interfacial charge separation and transport. In this Review, we aim to highlight the recent developments in CP-NC nanocomposite materials, critically examine the viable preparative strategies geared to craft intimate CP-NC nanocomposites and their photovoltaic performance in hybrid solar cells, and finally provide an outlook for future directions of this extraordinarily rich field.
机译:结合了共轭聚合物(CP)和纳米晶体(NC)的半导体有机-无机混合太阳能电池提供了以低成本制造实现高效能量转换的潜力。基于CP的光伏设备具有CP和NC广泛的一系列有利特性,例如CP的轻巧,灵活和可加工性,以及NC的高电子迁移率和尺寸相关的光学特性,这些都是对CP的补充。最近的研究已经见证了在将CP直接束缚在NC表面上以产生紧密接触的CP-NC纳米复合材料这一新兴领域中的快速发展,该复合材料具有定义明确的界面,可以显着促进NC在CP基质中的分散,促进光诱导的电荷转移在这两个半导体组件之间,为研究界面电荷的分离和传输提供了一个有效的平台。在本综述中,我们旨在重点介绍CP-NC纳米复合材料的最新发展,严格审查旨在制造紧密CP-NC纳米复合材料的可行制备策略及其在混合太阳能电池中的光伏性能,并最终为未来的发展方向提供展望这个异常丰富的领域。

著录项

  • 来源
    《Advanced Materials》 |2012年第32期|4353-4368|共16页
  • 作者

    Lei Zhao; Zhiqun Lin;

  • 作者单位

    School of Materials Science and Engineering Georgia Institute of Technology Atlanta, GA 30332, USA;

    School of Materials Science and Engineering Georgia Institute of Technology Atlanta, GA 30332, USA;

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  • 正文语种 eng
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