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Hybrid Polyester Coating Incorporating Functionalized Mesoporous Carriers for the Holistic Protection of Steel Surfaces

机译:杂化聚酯涂层结合功能化介孔载体对钢表面的整体保护

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摘要

Given the well-documented global corrosion challenge, the development of universal coating systems for metals that provide both passive and active protection is desirable. The active part of such systems typically consists of either polymer precursors or efficient corrosion inhibitors contained inside small capsules disseminated throughout the coating. In both cases, coating rupture and the onset of corrosion trigger a release of the active molecules, which can either physically repair the passive coating or form a thin impermeable film over the exposed metal surface. Previous work in our group has focused on the use of corrosion inhibitors; the technology is well-established for aluminium surfaces and typically employs a hybrid sol-gel film as the coating matrix. However, despite some effort, no similarly effective system has been found for steel.'4'11' When applied to steel the same sol-gel film tends to form a noticeably permeable coating that is highly susceptible to corrosive attack.'4' To improve the passive and active protection of steel, the coating matrix should be nonporous with excellent adhesion and incorporate well-dispersed capsules containing a suitable inhibitor in sufficient quantity. Dense polymer-based coatings are a good option for the passive layer; those incorporating inhibitor directly' or inside capsules have been found to provide excellent passive protection of steel surfaces whilst intact.
机译:鉴于有据可查的全球腐蚀挑战,因此需要开发一种既能提供被动保护又能提供主动保护的金属通用涂层系统。这种系统的活性部分通常由分散在整个涂层中的小胶囊内的聚合物前体或有效的腐蚀抑制剂组成。在这两种情况下,涂层破裂和腐蚀的发生都会触发活性分子的释放,从而可以物理修复钝化涂层或在裸露的金属表面上形成不渗透的薄膜。我们小组以前的工作集中在腐蚀抑制剂的使用上。该技术已经很好地用于铝表面,并且通常使用混合溶胶-凝胶薄膜作为涂层基质。然而,尽管付出了一些努力,仍未发现对钢具有类似有效的体系。'4'11'当应用于钢时,相同的溶胶-凝胶膜往往会形成明显可渗透的涂层,极易受到腐蚀侵蚀。'4'为了改善钢的被动和主动保护性能,涂层基体应该是无孔的,具有出色的附着力,并应充分分散分散的胶囊,其中应包含足够量的合适抑制剂。致密的聚合物基涂料是钝化层的不错选择。已经发现那些直接结合抑制剂或在胶囊内部结合的抑制剂可在完好无损的同时为钢表面提供出色的被动保护。

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  • 来源
    《Advanced Materials》 |2011年第11期|p.1361-1365|共5页
  • 作者单位

    Max-Plank for Colloids and Interfaces Wissenschaftspark Potsdam-Colm 14476 Potsdam, Germany;

    Max-Plank for Colloids and Interfaces Wissenschaftspark Potsdam-Colm 14476 Potsdam, Germany;

    Max-Plank for Colloids and Interfaces Wissenschaftspark Potsdam-Colm 14476 Potsdam, Germany;

    Max-Plank for Colloids and Interfaces Wissenschaftspark Potsdam-Colm 14476 Potsdam, Germany;

    Max-Plank for Colloids and Interfaces Wissenschaftspark Potsdam-Colm 14476 Potsdam, Germany;

    Max-Plank for Colloids and Interfaces Wissenschaftspark Potsdam-Colm 14476 Potsdam, Germany;

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