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A Versatile Low Bandgap Polymer for Air-Stable, High-Mobility Field-Effect Transistors and Efficient Polymer Solar Cells

机译:适用于空气稳定,高迁移率场效应晶体管和高效聚合物太阳能电池的多功能低带隙聚合物

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摘要

Polymer-based organic thin-film transistors (OTFTs) and organic photovoltaics (OPVs) have attracted much interest in recent years due to their solution processability and mechanical flexibility, which potentially allow them to be manufactured using low-cost, high-throughput processes such as roll-to-roll printing and inkjet printing. In recent years, the development of novel materials for these applications has contributed to significant improvements in device performance. In the field of OTFTs, the development of polythiophene derivatives such as poly(3,3-dialkyl-quaterthiophene) (PQT) and poly(2,5-bis(3-alkylthiophen-2-yl)thieno[3,2-b]thiophene) (PBTTT) has resulted in OTFTs with hole mobilities of between 0.2 and 0.6 cm~2V~(-1)s~(-1). The development of low bandgap polymer donors has meanwhile helped to lift solar cell power conversion efficiencies (PCEs) to above 6%. However, there have been few reports of polymers that perform well in both OTFTs and OPVs. The development of such versatile polymers could be beneficial for applications which incorporate both types of devices.
机译:近年来,基于聚合物的有机薄膜晶体管(OTFT)和有机光伏(OPV)引起了人们的极大兴趣,因为它们具有溶液加工性和机械柔韧性,这有可能使它们能够使用低成本,高通量的工艺来制造,例如卷对卷打印和喷墨打印。近年来,针对这些应用的新型材料的开发极大地改善了设备性能。在OTFT领域,开发了聚噻吩衍生物,例如聚(3,3-二烷基-四噻吩)(PQT)和聚(2,5-双(3-烷基噻吩-2-基)噻吩并[3,2-b (噻吩)(PBTTT)导致OTFT的空穴迁移率在0.2和0.6 cm〜2V〜(-1)s〜(-1)之间。同时,低带隙聚合物供体的发展有助于将太阳能电池的功率转换效率(PCE)提升至6%以上。但是,几乎没有关于在OTFT和OPV中均表现良好的聚合物的报道。这种多用途聚合物的开发对于结合两种类型的装置的应用可能是有益的。

著录项

  • 来源
    《Advanced Materials》 |2011年第11期|p.1409-1413|共5页
  • 作者单位

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore,Department of Chemistry Imperial College London Exhibition Road, London SW7 2AZ, UK;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

    Institute of Materials Research and Engineering 3 Research Link, Singapore 117602, Singapore;

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