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Oligomeric Phenylenevinylene with Cross Dipole Arrangement and Amorphous Morphology: Enhanced Solid-State Luminescence Efficiency and Electroluminescence Performance

机译:具有交叉偶极排列和无定形形态的低聚苯撑乙烯撑:增强的固态发光效率和电致发光性能

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摘要

OPVs, whose structures range from crystalline to an amorphous glass, are realized through a chemical construction, providing a new example of the impact of molecular structure on condensed structures and optical properties. The special structure of 3 also provides a model for theoretical studies, such as di-pole-dipole and exciton-exciton interactions in such a crosslinked chromophore system. OPV 3 behaves as an amorphous glass with excellent thermal and morphological stabilities, as well as a high solid luminescence, which makes it a promising candidate for blue electroluminescent materials and other optoelectronic device materials.
机译:OPV的结构范围从晶体到非晶玻璃,是通过化学结构实现的,为分子结构对凝聚结构和光学性质的影响提供了新的实例。 3的特殊结构还为理论研究提供了模型,例如在这种交联的生色团体系中的偶极-偶极和激子-激子相互作用。 OPV 3表现为具有出色的热和形态稳定性以及高固体发光度的无定形玻璃,这使其成为蓝色电致发光材料和其他光电器件材料的有希望的候选者。

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