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Hydrogen-Bonding-Directed Layer-by-Layer Assembly of Conjugated Polymers

机译：氢键引导的共​​轭聚合物的逐层组装

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摘要

There has been great interest recently in the development of a new generation of electronic and photonic devices based on π-conjugated polymers. These organic semiconductors, which exhibit tunable physical properties and are easily processed, have been explored to fabricate a wide variety of thin-film devices ranging from electronic and optoelectronic devices to mechanical actuators. Superlattice and heterogeneous structures of conducting polymers, in particular, are extremely interesting from the viewpoint of various electro-optical applications. For example, multilayered heterostruc-tures made up of conjugated polymers are being considered for use in photovoltaic energy-conversion systems due to the highly efficient charge separation at interfaces in the multilayer. To ultimately realize such devices, however, new techniques for manipulating these novel materials into large-area and layered thin films with precisely controlled thickness and molecular architecture are needed.
机译：最近，对基于π共轭聚合物的新一代电子和光子器件的开发引起了极大的兴趣。这些有机半导体显示出可调节的物理特性，并且易于加工，已经被研究用于制造从电子和光电器件到机械致动器的各种薄膜器件。从各种电光应用的角度来看，导电聚合物的超晶格和异质结构尤其令人关注。例如，由于在多层的界面处的高效电荷分离，因此考虑将由共轭聚合物组成的多层异质结构用于光伏能量转换系统。然而，为了最终实现这种装置，需要用于将这些新材料加工成具有精确控制的厚度和分子结构的大面积和分层薄膜的新技术。

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