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Pulse, Pump & Probe

机译:脉冲,泵和探头

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The essential change implicit in the arrow in a chemical reaction, A + B → C + D, may be rapid, it may be slow. I drop a small chunk of potassium into water, and the show is over in less than a second. The majestic copper beech outside my window was not noticeably smaller yesterday, but a photograph of it 75 years ago shows it just 10 feet high. Many biochemical reactions went into that slow growth. They tell me the universe is 15 billion years old, they tell me that the primary photochemical act in vision—a change in shape of a retinal molecule—transpires in 200 femtoseconds. (One femtosecond, fs, is 10~(-15) seconds—the name of the unit a relatively rare intrusion of a nice Scandinavian root into a scientific nomenclature generally too anxious to impress in Greek and Latin.) I sort of trust the former, I believe the latter, and in this third Marginalia on the new kinetic chemistry, I would like to tell you why.
机译:化学反应中箭头所隐含的本质变化A + B→C + D可能很快,可能很慢。我将一小撮钾盐倒入水中,演出不到一秒钟就结束了。昨天,我窗外的宏伟的铜山毛榉并没有明显变小,但是75年前的一张照片显示它只有10英尺高。许多生化反应进入了这种缓慢的增长。他们告诉我宇宙已有150亿年的历史,他们告诉我视觉中的主要光化学行为(视网膜分子形状的变化)在200飞秒内发生蒸发。 (一个飞秒fs是10〜(-15)秒-该装置的名称是相当罕见的斯堪的纳维亚根侵入科学命名法中的一种相对罕见的方法,通常太急于在希腊语和拉丁语中留下深刻的印象。)我有点相信前者,我相信是后者,在新的动力学化学的第三个Marginalia中,我想告诉你为什么。

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