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Electric double layers allow for opaque electrodes in high performance organic optoelectronic devices

机译:双电层允许在高性能有机光电器件中使用不透明电极

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摘要

We report that opaque electrodes can be used for high-performance organic optoelectronic devices, facilitated by the electric double layers (EDLs) formed in ionic liquids. For the photocell, gold/ poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-phenyl C_(61) butyric acid methyl ester (PCBM)/ionic liquid/silver, the EDLs enable a large photocurrent response, without the electrodes being superimposed. The external quantum efficiency and responsivity can reach 61.2% and 272 mA/W, respectively. The specific detectivity can reach 1.9 × 10~(13) Jones, which is larger than silicon-based detectors. This type of architecture will renew the operation principle and material choice for organic photocells, because transparency is no longer an indispensable condition for the electrodes.
机译:我们报告说,不透明电极可用于高性能有机光电器件,这是由离子液体中形成的双电层(EDL)促进的。对于光电池,金/聚(3-己基噻吩-2,5-二基)(P3HT):[6,6]-苯基C_(61)丁酸甲酯(PCBM)/离子液体/银,EDL使光电流响应大,而无需叠加电极。外部量子效率和响应度分别可以达到61.2%和272 mA / W。比探测率可以达到1.9×10〜(13)Jones,比硅基探测器要大。这种类型的体系结构将更新有机光电池的工作原理和材料选择,因为透明性不再是电极必不可少的条件。

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  • 来源
    《Applied Physics Letters》 |2012年第17期|173302.1-173302.5|共5页
  • 作者单位

    Department of Chemistry and Research Center for Materials Science, Nagoya University,Nagoya 464-8602, Japan,Department of Applied Physics, Zhejiang University of Technology, Hangzhou 310023,People's Republic of China;

    Department of Chemistry and Research Center for Materials Science, Nagoya University,Nagoya 464-8602, Japan;

    Department of Chemistry and Research Center for Materials Science, Nagoya University,Nagoya 464-8602, Japan;

    Department of Chemistry and Research Center for Materials Science, Nagoya University,Nagoya 464-8602, Japan;

    Department of Chemistry and Research Center for Materials Science, Nagoya University,Nagoya 464-8602, Japan;

    Department of Chemistry and Research Center for Materials Science, Nagoya University,Nagoya 464-8602, Japan,CREST, JST, Nagoya 464-8602, Japan;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
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  • 正文语种 eng
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