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Light-induced increase of nonradiative recombination centers in hydrogenated nanocrystalline silicon solar cells under reverse electric bias

机译:反向电偏压下光致氢化纳米晶硅太阳能电池非辐射复合中心的增加

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摘要

We studied photoluminescence (PL) of hydrogenated nanocrystalline silicon (nc-Si:H) solar cells in the annealed and light-soaked states under various electric biases during light soaking. PL intensity from grain boundaries decreased after light soaking under a reverse bias, which implies a reduction in the radiative recombination rate as a consequence of an increase in nonradiative recombination centers in grain-boundary regions. However, such PL change was not observed after light soaking under open-circuit condition. The results suggest that the reverse bias during light soaking enhanced metastable defect generation in the grain-boundary regions, which is consistent with the explanation in our previous nc-Si:H cell stability studies.
机译:我们研究了在光浸泡期间,在各种电偏压下,处于退火和光浸泡状态的氢化纳米晶硅(nc-Si:H)太阳能电池的光致发光(PL)。在反向偏压下光浸泡后,来自晶界的PL强度降低,这意味着由于晶界区域中非辐射复合中心的增加,导致辐射复合率降低。然而,在开路条件下浸光后未观察到这种PL变化。结果表明,光浸泡过程中的反向偏压增强了晶界区域中亚稳态缺陷的产生,这与我们先前的nc-Si:H细胞稳定性研究中的解释一致。

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  • 来源
    《Applied Physicsletters》 |2009年第2期|023506.1-023506.3|共3页
  • 作者单位

    Department of Physics, Boston College, Chestnut Hill, Massachusetts 02467, USA;

    Department of Physics, Boston College, Chestnut Hill, Massachusetts 02467, USA;

    United Solar Ovonic LLC, 1100 West Maple Road, Troy, Michigan 48084, USA;

    United Solar Ovonic LLC, 1100 West Maple Road, Troy, Michigan 48084, USA;

    United Solar Ovonic LLC, 1100 West Maple Road, Troy, Michigan 48084, USA;

    United Solar Ovonic LLC, 1100 West Maple Road, Troy, Michigan 48084, USA;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
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  • 正文语种 eng
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