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首页> 外文期刊>Applied physics >Photoluminescence characteristics and energy transfer between Bi~(3+) and Eu~(3+) in Gd_2O_3: Eu~(3+), Bi~(3+) nanophosphors
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Photoluminescence characteristics and energy transfer between Bi~(3+) and Eu~(3+) in Gd_2O_3: Eu~(3+), Bi~(3+) nanophosphors

机译:Gd_2O_3中Bi〜(3+)和Eu〜(3+)之间的发光特性和能量转移:Eu〜(3 +),Bi〜(3+)纳米磷光体

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摘要

Bi~(3+) and Eu~(3+) codoped cubic Gd_2O_3 nanocrys-tals were prepared by the Pechini sol-gel method. Their pho-toluminescent properties were investigated under ultraviolet light excitation. The introduction of Bi~(3+) ions broadened the excitation band of Eu~(3+) emission, of which a new strong band occurred ranging from 320 to 380 nm due to the 6s~2→ 6s6p transition of Bi~(3+) ions, implying a very efficient energy transfer from Bi~(3+) ions to Eu~(3+) ions. Upon 325 and 355 nm light excitation, the luminescent intensity of Eu~(3+) ions was remarkably improved by the incorporation of Bi~(3+) ions. But a significant quenching of Eu~(3+) emission was observed under 266 nm light excitation when Bi~(3+) was codoped. The possible energy transfer processes between Bi~(3+) and Eu~(3+) were discussed. The decay curves of Eu~(3+) emission under the excitation of 266 nm pulsed laser were measured and gave further evidence for our discussion.
机译:采用Pechini溶胶-凝胶法制备了Bi〜(3+)和Eu〜(3+)共掺杂的立方Gd_2O_3纳米晶。在紫外光激发下研究了它们的光致发光性能。 Bi〜(3+)离子的引入拓宽了Eu〜(3+)发射的激发带,由于Bi〜(3)的6s〜2→6s6p跃迁,其中一个新的强谱带出现在320至380 nm范围内+)离子,这意味着从Bi〜(3+)离子到Eu〜(3+)离子的能量转移非常有效。在325和355 nm的光激发下,掺入Bi〜(3+)离子显着提高了Eu〜(3+)离子的发光强度。但是,当Bi〜(3+)被共掺杂时,在266nm的光激发下,Eu〜(3+)的发射发生了明显的猝灭。讨论了Bi〜(3+)和Eu〜(3+)之间可能的能量转移过程。测量了266nm脉冲激光激发下Eu〜(3+)发射的衰减曲线,为我们的讨论提供了进一步的证据。

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  • 来源
    《Applied physics》 |2010年第4期|P.763-768|共6页
  • 作者单位

    Department of Physics, University of Science and Technology of China, Hefei 230026, China;

    rnDepartment of Physics, University of Science and Technology of China, Hefei 230026, China;

    rnDepartment of Physics, University of Science and Technology of China, Hefei 230026, China;

    rnDepartment of Physics, University of Science and Technology of China, Hefei 230026, China;

    rnDepartment of Physics, University of Science and Technology of China, Hefei 230026, China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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