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Outlook and challenges for hydrogen storage in nanoporous materials

机译:纳米多孔材料中储氢的前景和挑战

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摘要

Considerable progress has been made recently in the use of nanoporous materials for hydrogen storage. In this article, the current status of the field and future challenges are discussed, ranging from important open fundamental questions, such as the density and volume of the adsorbed phase and its relationship to overall storage capacity, to the development of new functional materials and complete storage system design. With regard to fundamentals, the use of neutron scattering to study adsorbed H_2, suitable adsorption isotherm equations, and the accurate computational modelling and simulation of H_2 adsorption are discussed. The new materials covered include flexible metal-organic frameworks, core-shell materials, and porous organic cage compounds. The article concludes with a discussion of the experimental investigation of real adsorptive hydrogen storage tanks, the improvement in the thermal conductivity of storage beds, and new storage system concepts and designs.
机译:最近在使用纳米孔材料进行氢存储方面已经取得了显着进展。本文讨论了该领域的现状和未来的挑战,范围从重要的开放性基本问题开始,例如吸附相的密度和体积及其与总存储容量的关系,到新功能材料的开发和完整应用。存储系统设计。关于基本原理,讨论了使用中子散射研究吸附的H_2,合适的吸附等温线方程以及H_2吸附的精确计算模型和模拟。涵盖的新材料包括柔性金属有机骨架,核壳材料和多孔有机笼状化合物。本文最后讨论了对实际吸附性氢储罐的实验研究,储层热导率的提高以及新的存储系统概念和设计。

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  • 来源
    《Applied Physics》 |2016年第3期|151.1-151.21|共21页
  • 作者单位

    Hiden Isochema Ltd, 422 Europa Boulevard, Warrington WA5 7TS, UK;

    Queensland Micro- and Nanotechnology Centre, Griffith University, Brisbane, Australia;

    National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, CO 80401, USA;

    National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, CO 80401, USA;

    National Renewable Energy Laboratory, 15013 Denver West Parkway, Golden, CO 80401, USA;

    Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA,Department of Chemical Engineering, University of Delaware, Newark, DE 19716, USA;

    Institut de Recherche sur l'hydrogene, Universite du Quebec a Trois-Rivieres, P. O. Box 500, Trois-Rivieres, QC G9A 5H7, Canada,Gas Processing Center, College of Engineering, Qatar University, P. O. Box 2713, Doha, Qatar;

    Department of Materials Science and Technology, University of Crete, P. O. Box 2208, 71003 Heraklion, Crete, Greece;

    Department of Chemistry, University of Crete, P. O. Box 2208, 71003 Heraklion, Crete, Greece;

    Department of Chemistry, University of Crete, P. O. Box 2208, 71003 Heraklion, Crete, Greece;

    Institute of Nanoscience and Nanotechnology, NCSR 'DEMOKRITOS', Aghia Paraskevi Attikis, 153 10 Athens, Greece;

    Department of Chemistry, University of Crete, P. O. Box 2208, 71003 Heraklion, Crete, Greece;

    Savannah River National Laboratory, Aiken, SC 29808, USA;

    Savannah River National Laboratory, Aiken, SC 29808, USA;

    Savannah River National Laboratory, Aiken, SC 29808, USA;

    Savannah River National Laboratory, Aiken, SC 29808, USA;

    United Technologies Research Center, 411 Silver Lane, East Hartford, CT 06118, USA;

    Institut de Recherche sur l'hydrogene, Universite du Quebec a Trois-Rivieres, P. O. Box 500, Trois-Rivieres, QC G9A 5H7, Canada;

    Institut de Recherche sur l'hydrogene, Universite du Quebec a Trois-Rivieres, P. O. Box 500, Trois-Rivieres, QC G9A 5H7, Canada;

    Max-Planck-Institut fuer Intelligente Systeme, Heisenbergstrasse 3, 70569 Stuttgart, Germany;

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