Isoconversion Effective Activation Energy Profiles by Variable Temperature Diffuse Reflection Infrared Spectroscopy

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Isoconversion Effective Activation Energy Profiles by Variable Temperature Diffuse Reflection Infrared Spectroscopy

机译：等温转换有效活化能谱的可变温度扩散反射红外光谱

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Thermal process characterization based on calculating effective activation energies from variable temperature diffuse reflection infrared spectroscopy (VT-DRIFTS) measurements is demonstrated. Experimental factors that affect the accuracies of activation energy values are outlined. Infrared radiation scattering efficiency, thermal conductivity, and inertness towards chemical reactions are factors that should be considered when selecting an appropriate diluent for preparing samples. The Kubelka–Munk representation is superior to apparent absorbance when baseline variations in spectra measured at different temperatures can be minimized. Variable-temperature infrared spectral features, such as integrated absorption band area, can be used to compute isoconversion effective activation energies, provided that measured quantities are proportional to species concentrations.

机译：演示了基于通过可变温度漫反射红外光谱（VT-DRIFTS）测量计算有效活化能的热过程表征。概述了影响活化能值准确性的实验因素。在选择合适的稀释剂用于制备样品时，应考虑红外辐射的散射效率，导热率和对化学反应的惰性。当可以最小化在不同温度下测量的光谱的基线变化时，Kubelka-Munk表示优于表观吸收。只要测量的量与物质浓度成正比，可变温度的红外光谱特征（例如积分吸收带面积）可用于计算等转换有效活化能。

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《Applied Spectroscopy》 |2008年第1期|116-120|共5页
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1. Isoconversion Effective Activation Energy Profiles by Variable Temperature Diffuse Reflection Infrared Spectroscopy [J] . DANIEL R. WHITE, ROBERT L. WHITE Applied Spectroscopy: Society for Applied Spectroscopy . 2008,第1期

机译：等温转换有效活化能谱的可变温度扩散反射红外光谱
2. A Variable-Temperature Diffuse Reflectance Infrared Fourier Transform Spectroscopy Study of the Binding of Water and Pyridine to the Surface of Acid-Activated Metakaolin [J] . Carolina Belver, Christopher Breen, Francis Clegg, Langmuir: The ACS Journal of Surfaces and Colloids . 2005,第6期

机译：水和吡啶与酸活化偏高岭土表面结合的可变温度漫反射红外傅里叶变换光谱研究
3. Kinetics of Dimethyl Methylphosphonate Adsorption and Decomposition on Zirconium Hydroxide Using Variable Temperature In Situ Attenuated Total Reflection Infrared Spectroscopy [J] . Jeon Seokmin, Schweigert Igor V, Pehrsson Pehr E., ACS applied materials & interfaces . 2020,第13期

机译：使用可变温度原位衰减全反射红外光谱法测定羟基膦酸盐的甲基膦酸盐的吸附和分解的动力学
4. Computer Calculations of Enhanced Diffusivity and Effective Activation Energy from Measured Profiles of Impurities in Silicon [C] . Dao Khac An International conference on diffusion in materials . 2001

机译：计算机计算增强扩散性和有效激活能量从硅中测量的杂质
5. A study of polymer tertiary structure in Langmuir monolayer films of poly(dimethyl siloxane) by time-of-flight secondary ion mass spectrometry, reflection-absorption Fourier transform infrared spectroscopy and high-resolution electron energy loss spectroscopy. [D] . Piwowar, Alan M. 2007

机译：通过飞行时间二次离子质谱，反射吸收傅里叶变换红外光谱和高分辨率电子能量损失光谱研究聚（二甲基硅氧烷）Langmuir单层膜中的聚合物三级结构。
6. A Comparison of Two Laboratories for the Measurement of Wood Dust Using Button Sampler and Diffuse Reflection Infrared Fourier-Transform Spectroscopy (DRIFTS) [O] . Madalina M. Chirila, Khachatur Sarkisian, Michael E. Andrew, -1

机译：使用按钮采样器和漫反射红外傅里叶变换光谱仪（DRIFTS）测量木屑的两个实验室的比较
7. Kinetics of Dimethyl Methylphosphonate Adsorption and Decomposition on Zirconium Hydroxide Using Variable Temperature In Situ Attenuated Total Reflection Infrared Spectroscopy [O] . -1

机译：使用可变温度的二甲基磷酸二甲基膦酰基膦酸盐吸附和分解的可变温度在原位衰减总反射红外光谱法
8. Fourier Transform Infrared Reflection Absorption Spectroscopy Study ofChemisorbed PF3 on Ni(111): Coverage and Temperature Dependence [R] . Guo, X., Yates, J. T., Agrawal, 1991

机译：Ni（111）上的化学吸附pF3的傅里叶变换红外反射吸收光谱研究：覆盖率和温度依赖性

Isoconversion Effective Activation Energy Profiles by Variable Temperature Diffuse Reflection Infrared Spectroscopy

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