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In-situ IR monitoring of the formation of Zr-fumarate MOF

机译:富马酸锆MOF形成的原位红​​外监测

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摘要

The in-situ IR technique was employed to monitor the crystallization process of Zr-fumarate (Zr-fum) MOF under real synthesis conditions. The results evidenced the participations of both modulator acid (HCOOH) and solvent (DMF) during the structural formation of Zr-fum MOF. This observation will contribute to the quest for understanding of the formation of structural defects in MOFs, which is a topic that is currently under intense investigation. (C) 2017 Elsevier B.V. All rights reserved.
机译:采用原位红外技术监测富马酸锆(Fr)MOF在实际合成条件下的结晶过程。结果证明在Zr-烟气MOF的结构形成过程中,调制酸(HCOOH)和溶剂(DMF)均参与。这种观察将有助于寻求了解MOF中结构缺陷的形成,而这一问题目前正在深入研究中。 (C)2017 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2017年第may15期|263-267|共5页
  • 作者单位

    CSIR, HySA Infrastruct Ctr Competence, 627 Meiring Naude Rd, ZA-0001 Brummeria, Pretoria, South Africa;

    CSIR, HySA Infrastruct Ctr Competence, 627 Meiring Naude Rd, ZA-0001 Brummeria, Pretoria, South Africa;

    CSIR, HySA Infrastruct Ctr Competence, 627 Meiring Naude Rd, ZA-0001 Brummeria, Pretoria, South Africa;

    CSIR, HySA Infrastruct Ctr Competence, 627 Meiring Naude Rd, ZA-0001 Brummeria, Pretoria, South Africa;

    CSIR, HySA Infrastruct Ctr Competence, 627 Meiring Naude Rd, ZA-0001 Brummeria, Pretoria, South Africa;

    Shanghai Inst Technol, Sch Chem & Environm Engn, Haiquan Rd, Shanghai 201418, Peoples R China;

    Shanghai Inst Technol, Sch Chem & Environm Engn, Haiquan Rd, Shanghai 201418, Peoples R China;

    Resolut Circle Pty Ltd, Johannesburg, South Africa;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Metal-organic frameworks; NMR spectroscopy; IR spectroscopy;

    机译:金属有机骨架;核磁共振光谱;红外光谱;

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