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首页> 外文期刊>Applied Surface Science >Tribological characteristics of bisphenol AF bis(diphenyl phosphate) as an antiwear additive in polyalkylene glycol and polyurea grease for significantly improved lubrication
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Tribological characteristics of bisphenol AF bis(diphenyl phosphate) as an antiwear additive in polyalkylene glycol and polyurea grease for significantly improved lubrication

机译:双酚AF双(磷酸二苯酯)作为聚亚烷基二醇和聚脲润滑脂中的抗磨添加剂的摩擦学特性,可显着改善润滑性

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摘要

A new antiwear additive of Bisphenol AF bis(diphenyl phosphate) (BAFDP) was synthesized and characterized. The tribological behaviors of the additive for polyalkylene glycol (PAG) and polyurea grease (PG) application in steel/steel contacts were evaluated on an Optimol SRV-IV oscillating reciprocating friction and wear tester at elevated temperature. The results revealed that BAFDP could drastically reduce friction and wear of sliding pairs in both PAG and also in PG at 100 degrees C. The tribological properties of BAFDP are superior to the normally used zinc dialkyldithiophosphate-based additive package (ZDDP) in PAG and PG. Moreover, BAFDP as additive for PAG and PG displays relatively significant tribological properties in temperature-ramp tests by performing well at 50-300 degrees C, indicating the excellent high temperature friction reduction and anti-wear capacity of BAFDP. XPS results showed that boundary lubrication films composed of Fe(OH)O, Fe3O4, FePO4, FeF2, FeF3, compounds containing the P-O bonds, nitrogen oxide, and so forth, were formed on the worn surface, which contributed to excellent friction reduction and antiwear performance. (C) 2015 Elsevier B.V. All rights reserved.
机译:合成并表征了一种新型的双酚AF双(磷酸二苯酯)抗磨添加剂(BAFDP)。使用Optimol SRV-IV往复式往复摩擦磨损测试仪在高温下评估了用于钢/钢接触件的聚亚烷基二醇(PAG)和聚脲油脂(PG)添加剂的摩擦学行为。结果表明,BAFDP可以在100摄氏度下显着减少PAG和PG中滑动副的摩擦和磨损。BAFDP的摩擦学性能优于PAG和PG中常用的基于二烷基二硫代磷酸锌的添加剂包(ZDDP) 。此外,BAFDP作为PAG和PG的添加剂,通过在50-300摄氏度下的良好性能在温度斜坡测试中显示出相对显着的摩擦学性能,这表明BAFDP具有出色的高温减摩性和抗磨性。 XPS结果表明,在磨损表面上形成了由Fe(OH)O,Fe3O4,FePO4,FeF2,FeF3,含有PO键的化合物,氮氧化物等组成的边界润滑膜,有助于降低摩擦和降低摩擦。抗磨性能。 (C)2015 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2016年第15期|145-153|共9页
  • 作者单位

    Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China|Univ Chinese Acad Sci, Beijing 100049, Peoples R China;

    Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China|Univ Chinese Acad Sci, Beijing 100049, Peoples R China;

    Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China;

    Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Phosphate; Antiwear additive; Friction reduction; Polyalkylene glycol; Polyurea grease;

    机译:磷酸盐;抗磨添加剂;减摩;聚亚烷基二醇;聚脲油脂;

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