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A facile electrodeposition process to fabricate corrosion-resistant superhydrophobic surface on carbon steel

机译:一种在碳钢上制造耐腐蚀超疏水表面的简便电沉积工艺

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摘要

Superhydrophobic Fe film with hierarchical microano papillae structures is prepared on C45 steel surface by one-step electrochemical method. The superhydrophobic surface was measured with a water contact angle of 160.5 +/- 0.5 degrees and a sliding angle of 2 +/- 0.5 degrees. The morphology of the fabricated surface film was characterized by field emission scanning electron microscopy (FE-SEM), and the surface structure seems like accumulated hierarchical micro-nano scaled particles. Furthermore, according to the results of Fourier transform infrared spectra (FT-IR) and X-ray photoelectron spectroscopy (XPS), the chemical composition of surface film was iron complex with organic acid. Besides, the electrochemical measurements showed that the superhydrophobic surface improved the corrosion resistance of carbon steel in 3.5 wt.% NaCl solution significantly. The superhydrophobic layer can perform as a barrier and provide a stable air-liquid interface which inhibit penetration of corrosive medium. In addition, the as-prepared steel exhibited an excellent self-cleaning ability that was not favor to the accumulation of contaminants. (C) 2016 Elsevier B.V. All rights reserved.
机译:通过一步法在C45钢表面制备了具有分层的微纳米纳米乳头结构的超疏水Fe膜。测量超疏水性表面的水接触角为160.5 +/- 0.5度,滑动角为2 +/- 0.5度。用场发射扫描电子显微镜(FE-SEM)表征了制备的表面膜的形貌,表面结构看起来像是累积的分层的微纳米级颗粒。此外,根据傅立叶变换红外光谱(FT-IR)和X射线光电子能谱(XPS)的结果,表面膜的化学成分为铁与有机酸的络合物。此外,电化学测量表明,超疏水表面显着提高了碳钢在3.5 wt。%NaCl溶液中的耐腐蚀性。超疏水层可充当屏障并提供稳定的气液界面,从而抑制腐蚀性介质的渗透。另外,所制备的钢表现出优异的自清洁能力,不利于污染物的积累。 (C)2016 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2016年第15期|435-442|共8页
  • 作者单位

    Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Rd 8, Chengdu 610500, Sichuan Provinc, Peoples R China|Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan Provinc, Peoples R China;

    Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Rd 8, Chengdu 610500, Sichuan Provinc, Peoples R China|Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan Provinc, Peoples R China;

    Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Rd 8, Chengdu 610500, Sichuan Provinc, Peoples R China;

    Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan Provinc, Peoples R China;

    Southwest Petr Univ, Sch Chem & Chem Engn, Chengdu 610500, Sichuan Provinc, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Superhydrophobicity; Electrodeposition; Carbon steel; Corrosion; Self-cleaning;

    机译:超疏水性;电沉积;碳钢;腐蚀;自清洁;

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