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Light-emitting structures of CdS nanocrystals in oxidized macroporous silicon

机译:氧化大孔硅中CdS纳米晶体的发光结构

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摘要

Structured silicon substrates (macroporous silicon) with SiO2 nanolayers and CdS nanocrystals were proposed to reduce the flow of electrons and recombination outside the nanoparticle layer. It was found that the resonance electron scattering in samples with low concentration of Si-O-Si states transforms into ordinary scattering on ionized impurities for samples with high concentration of Si-O-Si states. The maximal intensity of photoluminescence was measured for a structure with maximum strength of the local electric field at the Si-SiO2 interface, indicating a significant decrease of non-radiative recombination in CdS nanocoating due to the flow of electrons from the silicon matrix towards the CdS nanocrystal layer. The quantum yield of photoluminescence increases with time due to evaporation of water molecules. (C) 2016 Elsevier B.V. All rights reserved.
机译:提出了具有SiO2纳米层和CdS纳米晶体的结构化硅衬底(大分子硅),以减少电子流和纳米颗粒层外的复合。结果发现,低浓度Si-O-Si态样品中的共振电子散射转化为高浓度Si-O-Si态样品中离子杂质的普通散射。测量了在Si-SiO2界面处具有最大电场强度的结构的最大光致发光强度,这表明由于电子从硅基体流向CdS,CdS纳米涂层中的非辐射复合显着减少。纳米晶体层。由于水分子的蒸发,光致发光的量子产率随时间增加。 (C)2016 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Applied Surface Science》 |2016年第ptaa期|288-293|共6页
  • 作者单位

    Ningbo Univ Technol, 55-155 Cui Bai Rd, Ningbo 315016, Zhejiang, Peoples R China|NAS Ukraine, V Lashkaryov Inst Semicond Phys, 41 Nauki Pr, UA-03028 Kiev, Ukraine;

    NAS Ukraine, L Pisarzhevsky Inst Phys Chem, 31 Nauki Pr, UA-03028 Kiev, Ukraine;

    NAS Ukraine, L Pisarzhevsky Inst Phys Chem, 31 Nauki Pr, UA-03028 Kiev, Ukraine;

    NAS Ukraine, V Lashkaryov Inst Semicond Phys, 41 Nauki Pr, UA-03028 Kiev, Ukraine;

    NAS Ukraine, V Lashkaryov Inst Semicond Phys, 41 Nauki Pr, UA-03028 Kiev, Ukraine;

    NAS Ukraine, V Lashkaryov Inst Semicond Phys, 41 Nauki Pr, UA-03028 Kiev, Ukraine;

    Ningbo Univ Technol, 55-155 Cui Bai Rd, Ningbo 315016, Zhejiang, Peoples R China;

    Ningbo Univ Technol, 55-155 Cui Bai Rd, Ningbo 315016, Zhejiang, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Photoluminescence; CdS nanocrystals; Oxidized macroporous silicon;

    机译:光致发光CdS纳米晶体氧化大孔硅;

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