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Preparation and characterization of boron-doped titania nano-materials with antibacterial activity

机译:具有抗菌活性的掺硼二氧化钛纳米材料的制备与表征

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摘要

Boron-doped TiO_2 (B/TiO_2) nano-materials were synthesized by a sol-gel method and characterized by X-ray diffraction pattern (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectrum (FT-IR) and UV-vis diffuse reflectance spectra (DRS). With the test of bacterial inhibition zone, the antibacterial properties of B/TiO_2 nano-materials on Escherichia coli were investigated. The results show that the structure of TiO_2 could be transformed from amorphous to anatase and then to rutile by increasing calcination temperature; part of the boron atoms probably have been weaved into the interstitial TiO_2 structure or incorporated into the TiO_2 lattice through occupying O sites, whereas others exist as B_2O_3. The results of antibacterial experiment under visible light irradiation show that the B/TiO_2 nano-materials exhibit enhanced antibacterial efficiency compared with non-doped TiO_2. Ultimately, the action mechanism of B/TiO_2 doping is discussed.
机译:溶胶-凝胶法合成了硼掺杂的TiO_2(B / TiO_2)纳米材料,并通过X射线衍射图谱(XRD),透射电子显微镜(TEM),X射线光电子能谱(XPS),傅里叶变换进行了表征。红外光谱(FT-IR)和紫外可见漫反射光谱(DRS)。通过细菌抑菌圈试验,研究了B / TiO_2纳米材料对大肠杆菌的抗菌性能。结果表明,通过提高煅烧温度,可以使TiO_2的结构从无定形转变为锐钛矿,再转变为金红石。硼原子的一部分可能已被编织到间隙TiO_2结构中或通过占据的O位置并入TiO_2晶格,而其他硼原子以B_2O_3的形式存在。可见光照射下的抗菌实验结果表明,与未掺杂的TiO_2相比,B / TiO_2纳米材料具有更高的抗菌效率。最终,讨论了B / TiO_2掺杂的作用机理。

著录项

  • 来源
    《Applied Surface Science》 |2013年第1期|94-99|共6页
  • 作者单位

    Institute of Metallurgical Resources and Environmental Engineering, Northeastern University, Shenyang 110819, China,Liaoning Engineering and Technology Research Center of Boron Resources Comprehensive Utilization, Shenyang 110819, China,Liaoning Engineering and Technology Research Center of Boron Resources Comprehensive Utilization, Shenyang 110819, China,Liaoning Provincial Universities Key Laboratory of Boron Resources Ecological Utilization Technology and Boron Materials, Shenyang 110819, China;

    Institute of Metallurgical Resources and Environmental Engineering, Northeastern University, Shenyang 110819, China,Liaoning Key Laboratory of Metallurgical Resources Recycling Science, Shenyang 110819, China,Liaoning Engineering and Technology Research Center of Boron Resources Comprehensive Utilization, Shenyang 110819, China,Liaoning Provincial Universities Key Laboratory of Boron Resources Ecological Utilization Technology and Boron Materials, Shenyang 110819, China;

    Institute of Metallurgical Resources and Environmental Engineering, Northeastern University, Shenyang 110819, China,Liaoning Key Laboratory of Metallurgical Resources Recycling Science, Shenyang 110819, China,Liaoning Engineering and Technology Research Center of Boron Resources Comprehensive Utilization, Shenyang 110819, China,Liaoning Provincial Universities Key Laboratory of Boron Resources Ecological Utilization Technology and Boron Materials, Shenyang 110819, China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    boron doping; titania nanoparticle; antimicrobial activity; visible light;

    机译:硼掺杂二氧化钛纳米粒子抗菌活性可见光;

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