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Influence of interface modification on the performance of polymer/Bi_2S_3 nanorods bulk heterojunction solar cells

机译:界面改性对聚合物/ Bi_2S_3纳米棒整体异质结太阳能电池性能的影响

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摘要

In this paper, bulk heterojunction photovoltaic devices based on the poly@@[2-methoxy-5-(3',7-dimethyloctyloxy)-1,4-phenylenevinylene] (MDMO-PPV):Bi2S3 nanorods hybrid material were present. To optimize the performance of the devices, the interface modification of the hybrid material that has a significant impact on the exciton dissociation efficiency was studied. An improvement in the device performance was achieved by modifying the Bi_2S_3 surface with a thin dye layer. Moreover, modifying the Bi_2S_3 surface with anthracene-9-carboxylic acid can enhance the performance further. Compared with the solar cells with Bi_2S_3 nanorods hybrid with the MDMO-PPV as the active layer, the anthracene-9-carboxylic acid modified devices are better in performance, with the power conversion efficiency higher by about one order in magnitude.
机译:本文提出了一种基于聚@ [2-甲氧基-5-(3',7-二甲基辛氧基)-1,4-亚苯基亚乙烯基](MDMO-PPV):Bi2S3纳米棒杂化材料的本体异质结光伏器件。为了优化器件的性能,研究了对激子离解效率有重大影响的杂化材料的界面改性。通过用薄的染料层修饰Bi_2S_3表面,可以提高设备性能。此外,用蒽-9-羧酸修饰Bi_2S_3表面可以进一步提高性能。与具有以MDMO-PPV作为活性层的Bi_2S_3纳米棒混合的太阳能电池相比,蒽9-羧酸改性器件的性能更好,功率转换效率提高了一个数量级。

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  • 来源
    《Applied Surface Science》 |2010年第2期|p.423-428|共6页
  • 作者单位

    Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, People's Republic of China;

    Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, People's Republic of China;

    Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, People's Republic of China;

    College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People's Republic of China;

    Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, People's Republic of China;

    Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, People's Republic of China;

    Key Laboratory of Semiconductor Materials Science, Institute of Semiconductors, Chinese Academy of Sciences, Beijing 100083, People's Republic of China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    bulk heterojunction solar cells; surface modification; nanorods;

    机译:体异质结太阳能电池;表面改性;纳米棒;

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