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Characterization of copper SERS-active substrates prepared by electrochemical deposition

机译:通过电化学沉积制备的铜SERS活性基材的表征

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Surface Enhanced Raman Scattering (SERS) on copper substrates of various morphologies, prepared by electrochemical deposition on platinum targets, was investigated. The substrate preparation procedures differed by the coating bath compositions, applied current densities and the duration of individual steps. The surface morphology of the substrates was visualized by means of Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM). SERS spectra of selected organic thiols were measured and the relation between SERS spectral intensity and the surface structure of SERS-active substrates was studied. It has been shown that good Raman surface enhancement can be achieved on the copper substrates prepared by electrochemical deposition from ammoniac baths. Copper substrates fabricated from acidic baths did not show efficient Raman surface enhancement. The results of microscopic measurements demonstrated that the average surface roughness value does not play a substantial role, whereas the shape of the surface nanostructures is a key parameter.
机译:研究了通过电化学沉积在铂靶上制备的各种形态的铜基板上的表面增强拉曼散射(SERS)。底物制备程序的不同之处在于涂布浴的组成,施加的电流密度和各个步骤的持续时间。借助原子力显微镜(AFM)和扫描电子显微镜(SEM)观察基材的表面形态。测量了所选有机硫醇的SERS光谱,研究了SERS光谱强度与SERS活性底物表面结构的关系。已经表明在通过从氨浴中电化学沉积制备的铜基板上可以实现良好的拉曼表面增强。由酸性镀液制成的铜基材未显示出有效的拉曼表面增强性能。显微测量的结果表明,平均表面粗糙度值没有实质性作用,而表面纳米结构的形状是关键参数。

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