Preparation Of Well-defined Polymer-silicon Wafer Hybrids Via Surface-initiated Raft-mediated Process

Liang Li; Entang Kang; Koongee Neoh

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Preparation Of Well-defined Polymer-silicon Wafer Hybrids Via Surface-initiated Raft-mediated Process

机译：通过表面引发的木筏介导的过程制备明确的聚合物-硅晶片杂化体

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A simple method was developed for the immobilization of reversible addition-fragmentation chain-transfer (RAFT) initiators on the silicon surface. Well-defined polymer-silicon hybrids, including the tethered brushes of glycidyl methacrylate (GMA) polymer, poly(ethylene glycol) monomethacrylate (PEGMA) polymer and block copolymer on a silicon wafer, were prepared via surface-initiated RAFT living radical polymerization. The "living" chain ends were used as the macroinitiator for the subsequent synthesis of diblock copolymers.

机译：开发了一种简单的方法将可逆加成-断裂链转移（RAFT）引发剂固定在硅表面上。通过表面引发的RAFT活性自由基聚合反应制备了明确定义的聚合物-硅杂化物，包括甲基丙烯酸缩水甘油酯（GMA）聚合物的束缚刷，聚乙二醇单甲基丙烯酸酯（PEGMA）聚合物和硅晶片上的嵌段共聚物。 “活性的”链端被用作随后的二嵌段共聚物合成的大分子引发剂。

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来源
《Applied Surface Science》 |2008年第9期|p.2600-2604|共5页
作者
Liang Li; Entang Kang; Koongee Neoh;
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作者单位

Department of Chemical and Biomolecular Engineering, National University of Singapore, Kent Ridge, Singapore 119260, Singapore;

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原文格式 PDF
正文语种 eng
中图分类应用物理学;
关键词
surface-initiated raft; silicon; diblock copolymer;

机译：表面引发的筏;硅;二嵌段共聚物;

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专利

1. COVALENT IMMOBILIZATION OF GLUCOSE OXIDASE ON WELL-DEFINED POLYMER-SILICON WAFER HYBRIDS VIA SURFACE-INITIATED RAFT-MEDIATED PROCESS [J] . JI JIAYOU, XIA KEQIANG, LIU TINGTING, Journal of the Chilean Chemical Society . 2013,第3期

机译：通过表面引发的筏介导过程在定义良好的聚合物-硅晶片混合体中共价固定葡萄糖氧化酶
2. Surface-Initiated Atom Transfer Radical Polymerization for the Preparation of Well-Defined Organic–Inorganic Hybrid Nanomaterials [J] . Monika Flejszar, Pawe? Chmielarz Materials . 2019,第18期

机译：表面引发的原子转移自由基聚合制备精细定义的有机-无机杂化纳米材料
3. Surface-initiated atom transfer radical polymerization from halogen-terminated Si(111) (Si-X, X = Cl, Br) surfaces for the preparation of well-defined polymer-Si hybrids [J] . Xu FJ, Cai QJ, Kang ET, Langmuir: The ACS Journal of Surfaces and Colloids . 2005,第8期

机译：由卤素封端的Si（111）（Si-X，X = Cl，Br）表面引发的表面引发的原子转移自由基聚合，用于制备定义明确的聚合物-Si杂化物
4. Well-Defined Amphiphilic Polymer-Si(100) Hybrids via Surface-Initiated Atom Transfer Radical Polymerization [C] . Jin-Wen Peng, Rui-Hua Mo, Zhen-Fan Liu, China International Nanoscience and Technology Symposium . 2013

机译：通过表面引发的原子转移自由基聚合的明确定义的两亲聚合物-Si（100）杂种
5. Synthesis of novel polypeptide -silica hybrid materials through surface-initiated N-carboxyanhydride polymerization [D] . Lunn, Jonathan David 2010

机译：通过表面引发的N-羧基酸酐聚合合成新型多肽-二氧化硅杂化材料
6. Surface-Initiated Atom Transfer Radical Polymerization for the Preparation of Well-Defined Organic–Inorganic Hybrid Nanomaterials [O] . Monika Flejszar, Paweł Chmielarz 2019

机译：表面引发的原子转移自由基聚合制备精细定义的有机-无机杂化纳米材料
7. Surface-Initiated Atom Transfer Radical Polymerization from Halogen-Terminated Si(111) (Si-X, X = Cl, Br) Surfaces for the Preparation of Well-Defined Polymer-Si Hybrids [O] . -1

机译：表面引发的原子从卤素封端的Si（111）（Si-x，X = Cl，Br）表面转移自由基聚合，用于制备明确定义的聚合物 - Si杂种物

Preparation Of Well-defined Polymer-silicon Wafer Hybrids Via Surface-initiated Raft-mediated Process

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