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Preparation Of Silver Nanoparticles By Laser Ablation In Polyvinylpyrrolidone Solutions

机译:聚乙烯吡咯烷酮溶液中激光烧蚀制备银纳米颗粒

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We performed laser ablation of a silver plate in polyvinylpyrrolidone (PVP) aqueous solutions to prepare silver nanoparticles. Secondary laser irradiation onto the prepared colloidal solutions was also carried out. It was revealed that the formation efficiency was increased by addition of PVP as well as the stability of nanoparticles. The result of shadowgraph measurements suggested that the increased ablation efficiency by PVP is attributable to increased secondary etching efficiency by the solvent - confined plasma toward the silver plate. On the other hand, the size decrease of the nanoparticles by addition of PVP was more remarkable during the secondary irradiation process than in the laser ablation (nanoparticle preparation) process. This result indicates that emitted materials interact less sufficiently with PVP molecules in the laser ablation process than in the secondary laser irradiation process.
机译:我们在聚乙烯吡咯烷酮(PVP)水溶液中对银板进行激光烧蚀,以制备银纳米颗粒。还对制备的胶体溶液进行了二次激光照射。揭示了通过添加PVP以及纳米颗粒的稳定性提高了形成效率。阴影图测量的结果表明,PVP增加的烧蚀效率归因于溶剂限制的等离子体向银板的二次蚀刻效率增加。另一方面,在二次照射过程中,通过添加PVP使纳米颗粒的尺寸减小比在激光烧蚀(纳米颗粒制备)过程中更显着。该结果表明,与第二激光照射过程相比,在激光烧蚀过程中发射的材料与PVP分子的相互作用不足。

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