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Hybrid Bulk Heterojunction Solar Cells From A Blend Of Poly(3-hexylthiophene) And Tio_2 Nanotubes

机译:聚(3-己基噻吩)和Tio_2纳米管的混合物的混合体异质结太阳能电池。

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摘要

Hybrid bulk heterojunction solar cells based on blend of poly(3-hexylthiophene) (P3HT) and TiO_2 nanotubes or dye(N719) modified TiO_2 nanotubes were processed from solution and characterized to research the nature of organic/inorganic hybrid materials. Compared with the pristine polymer P3HT and TiO_2 nanoparticles/P3HT solar cells, the TiO_2 nanotubes/P3HT hybrid solar cells show obvious performance improvement, due to the formation of the bulk heterojunction and charge transport improvement. A further improvement in the device performance can be achieved by modifying TiO_2 nanotube surface with a standard dye N719 which can play a role in the improvement of both the light absorption and charge dissociation. Compared with the non-modified TiO_2 nanotubes solar cells, the modified ones have better power conversion efficiency under 100mW/cm~2 illumination with 500 W Xenon lamp.
机译:从溶液中加工了基于聚(3-己基噻吩)(P3HT)和TiO_2纳米管或染料(N719)改性的TiO_2纳米管的混合体杂化异质结太阳能电池,并对其进行了表征,以研究有机/无机杂化材料的性质。与原始聚合物P3HT和TiO_2纳米颗粒/ P3HT太阳能电池相比,由于形成了本体异质结和电荷传输的改善,TiO_2纳米管/ P3HT混合太阳能电池表现出明显的性能改善。可以通过用标准染料N719修饰TiO_2纳米管表面来实现器件性能的进一步提高,该染料可以在光吸收和电荷离解的改善中发挥作用。与未经修饰的TiO_2纳米管相比,经500W氙气灯在100mW / cm〜2的照度下,其具有更高的功率转换效率。

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