Optical Properties Of Thiol Terminated Biphenyloxazole Ordered monolayers On Gold Surface

A.V. Kukhta; I.N. Kukhta; E.E. Kolesnik; A.P. Lugovskii; O.L. Neyra; E. Meza

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Optical Properties Of Thiol Terminated Biphenyloxazole Ordered monolayers On Gold Surface

机译：巯基封端的联苯并恶唑有序单层在金表面的光学性质

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New thiol terminated biphenyloxazole molecules are synthesized. A self assembled monolayer has been prepared on gold surface and spectral and luminescent properties of free molecules and ordered films have been studied experimentally and theoretically (DFT). The luminescence polarization degree is about 40%. New absorption and luminescence bands have been found experimentally and confirmed theoretically. The highest occupied and the lowest unoccupied molecular orbitals of adsorbed molecules strongly differ from not adsorbed thiol molecules.

机译：合成了新的巯基封端的联苯恶唑分子。已经在金表面上制备了自组装单层，并且对自由分子的光谱和发光性质以及有序薄膜进行了实验和理论研究（DFT）。发光偏振度约为40％。通过实验发现了新的吸收和发光带，并在理论上得到了证实。吸附的分子的最高占据和最低的未占据分子轨道与未吸附的硫醇分子有很大的不同。

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来源
《Applied Surface Science》 |2007年第1期|p.116-119|共4页
作者
A.V. Kukhta; I.N. Kukhta; E.E. Kolesnik; A.P. Lugovskii; O.L. Neyra; E. Meza;
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作者单位

Institute of Molecular and Atomic Physics, NAS of Belarus, Nezalezhnastsi Ave. 70, 220072 Minsk, Belarus;

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原文格式 PDF
正文语种 eng
中图分类应用物理学;
关键词
biphenyloxazole; thiol; sam; polarization; absorption and luminescence spectrum; dft calculation;

机译：联苯并恶唑;硫醇;山姆;极化;吸收和发光光谱;dft计算;

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1. Self-assembled monolayers of fluorene- and nitrofluorene-terminated thiols on polycrystalline gold electrode: Electrochemical and optical properties [J] . Pak F, Meral K, Altundas R, Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2011,第1a2期

机译：多晶金电极上芴和硝基芴封端的硫醇的自组装单层：电化学和光学性质
2. On the Monolayer Adsorption of Thiol-Terminated Dendritic Oligothiophenes onto Gold Surfaces [J] . Guoqian Jiang, Suxiang Deng, Akira Baba, Macromolecular Chemistry and Physics . 2010,第24期

机译：巯基封端的树枝状寡聚噻吩在金表面的单层吸附
3. On the monolayer adsorption of thiol-terminated dendritic oligothiophenes onto gold surfaces [J] . Jiang G., Deng S., Baba A., Macromolecular chemistry and physics . 2010,第24期

机译：巯基封端的树枝状低聚噻吩在金表面的单层吸附
4. ELASTIC, ADHESIVE, AND CHARGE TRANSPORT PROPERTIES OF METHYL-TERMINATED ALKYLTHIOL SELF-ASSEMBLED MONOLAYERS ON GOLD SURFACES [C] . Frank W. DelRio, Cherno Jaye, Daniel A. Fischer, Annual meeting of the Adhesion Society . 2012

机译：金表面上甲基末端的烷基硫醇自组装单分子膜的弹性，吸附和电荷传输性质
5. Synthesis and characterization of alkoxyaniline-terminated monomer monolayers on gold surfaces (Conductive polymers). [D] . Schomburg, Keith Cory. 2000

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6. Multi-technique Characterization of Self-assembled Carboxylic Acid Terminated Alkanethiol Monolayers on Nanoparticle and Flat Gold Surfaces [O] . Sirnegeda D. Techane, Lara J. Gamble, David G. Castner -1

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7. Modification of electrode surfaces by self-assembled monolayers of thiol-terminated oligo(phenyleneethynylene)s.\ud [O] . Kaur, I., Zhao, X. T., Bryce, M. R., 2013

机译：巯基封端的低聚（亚苯基亚乙炔基）s的自组装单层修饰电极表面。

Optical Properties Of Thiol Terminated Biphenyloxazole Ordered monolayers On Gold Surface

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