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Columnar-grown porous films of lithium manganese oxide spinel (LiMn2O4) prepared by ultrasonic spray deposition

机译:超声喷涂沉积制备的柱状锂锰尖晶石多孔膜(LiMn2O4)

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Using LiNO3 and Mn(Ac)(2) as raw materials, ultrasonic spray deposition (USD) technique was used to fabricate LiMn2O4 films on platinum substrate at different substrate temperatures from 310 to 390 degrees C. The prepared thick films were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Electrochemical performance of the USD-derived films was also evaluated with LiMn2O4/Li cells. It is found that all of the LiMn2O4 films are porous and composed of orderly oriented columnar particles. The substrate temperature affects the fine microstructure of the columnar particles. The film prepared at 360 degrees C substrate temperature give rise to best electrochemical behavior. (c) 2005 Elsevier B.V. All rights reserved.
机译:以LiNO3和Mn(Ac)(2)为原料,采用超声波喷涂(USD)技术在310至390摄氏度的不同衬底温度下在铂衬底上制备LiMn2O4膜。射线衍射(XRD)和扫描电子显微镜(SEM)。用LiMn2O4 / Li电池还评估了USD衍生膜的电化学性能。发现所有的LiMn 2 O 4膜都是多孔的并且由有序取向的柱状颗粒组成。基底温度影响柱状颗粒的精细微观结构。在360摄氏度的基材温度下制备的薄膜具有最佳的电化学性能。 (c)2005 Elsevier B.V.保留所有权利。

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