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Electronic structure of gadolinium calcium oxoborate

机译:硼酸钙的电子结构

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Gadolinium calcium oxoborate (GdCOB) is a nonlinear optical material that belongs to the calcium-rare-earth (R) oxoborate family, with general composition Ca4RO(BO3)(3) (R3+ = La, Sm, Gd, Lu, Y). X-ray photoemission was applied to study the valence band electronic structure and surface chemistry of this material. High resolution photoemission measurements on the valence band electronic structure and Gd 3d and 4d, Ca 2p, B 1s and O 1s core lines were used to evaluate the surface and near surface chemistry. These results provide measurements of the valence band electronic structure and surface chemistry of this rare-earth oxoborate. (c) 2005 Elsevier B.V. All rights reserved.
机译:ox硼酸高硼酸钙(GdCOB)是一种非线性光学材料,属于稀土硼酸(R)硼酸钙家族,一般成分为Ca4RO(BO3)(3)(R3 + = La,Sm,Gd,Lu,Y)。 X射线光致发光被用于研究该材料的价带电子结构和表面化学。在价带电子结构和Gd 3d和4d,Ca 2p,B 1s和O 1s核心线上进行高分辨率光发射测量,以评估表面和近表面化学性质。这些结果提供了该稀土草酸盐的价带电子结构和表面化学的测量。 (c)2005 Elsevier B.V.保留所有权利。

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