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Effect of the solvent on the formation of n-dodecanethiol films on a polycrystalline Ag_(90)Ni_(10) substrate

机译:溶剂对多晶Ag_(90)Ni_(10)衬底上正十二烷硫醇薄膜形成的影响

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摘要

This paper reports the study of the solvent (ethanol, toluene, acetonitrile and carbon tetrachloride) effect on the self-assembling of alkanethiol monolayers on a polished and electroreduced Ag_(90)Ni_(10) alloy. Good quality organic films on such substrates are obtained from ethanolic solutions (n-dodecanethiol: 10~(-1) M, reaction time: 16 h). With similar reaction conditions, carbon tetrachloride leads to films of poor quality, while the organic layers formed from acetonitrile and toluene solutions are of intermediate quality.
机译:本文报道了在抛光和电还原的Ag_(90)Ni_(10)合金上,溶剂(乙醇,甲苯,乙腈和四氯化碳)对烷硫醇单层自组装作用的研究。从乙醇溶液(正十二烷硫醇:10〜(-1)M,反应时间:16小时)可在此类基材上获得高质量的有机膜。在相似的反应条件下,四氯化碳会导致薄膜质量下降,而由乙腈和甲苯溶液形成的有机层则处于中等质量。

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