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Nanoflakes of zinc oxide:cobalt oxide composites by pulsed laser fragmentation for visible light photocatalysis

机译:脉冲激光裂解制备的氧化锌:氧化钴复合材料纳米薄片,用于可见光光催化

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摘要

Metal oxide nanomaterials as visible light photocatalysts are of special interest for the research community. We report synthesis and properties of nanocomposites of zinc oxide with cobalt oxide by cryomilling followed by pulsed laser fragmentation technique for the first time. Structure, morphology, composition, optical properties and visible light photocatalysis of these nanocomposites are investigated. Morphological analysis showed that pulsed laser fragmentation in water resulted with nanoflakes. The optical absorption in visible range was enhanced by addition of cobalt oxide. Chemical states and mapping studies of the sample surfaces showed their uniformity of elemental composition. They were used for photocatalytic studies under visible light from a solar simulator (200 W) using methylene blue dye as the contaminant. These nanocomposites showed good stability and cyclic photocatalytic activity under visible light irradiation. The results show enhanced and cyclic visible light photocatalytic activities of metal oxide nanocomposites designed by pulsed laser fragmentation.
机译:金属氧化物纳米材料作为可见光光催化剂受到研究界的特别关注。我们首次报道了通过低温研磨和脉冲激光破碎技术对氧化锌和氧化钴的纳米复合材料的合成和性能。研究了这些纳米复合材料的结构,形态,组成,光学性质和可见光光催化作用。形态分析表明,水中的脉冲激光破碎是由纳米薄片引起的。通过添加氧化钴增强了可见光范围内的光吸收。样品表面的化学状态和作图研究表明其元素组成的均一性。它们被用于太阳光模拟器(200 W)在可见光下的光催化研究,使用亚甲基蓝染料作为污染物。这些纳米复合材料在可见光照射下显示出良好的稳定性和循环光催化活性。结果表明,通过脉冲激光破碎设计的金属氧化物纳米复合材料具有增强的循环可见光光催化活性。

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