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Self-assembly of ZnO nanoparticles attached to 3D pleated Zn_3(PO_4)_2/C from cola for enhanced lithium storage

机译:ZnO纳米粒子的自组装与可乐的3D褶皱Zn_3(PO_4)_2 / C结合,可增强锂的存储

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摘要

We reported an efficient and cost-effective strategy for self-assembly of ZnO nanoparticles attached to 3D pleated Zn-3(PO4)(2)/C from cola (ZnO/Zn-3(PO4)(2)/C). Wherein, 3D pleated Zn-3(PO4)(2)/C conductive buffer and ZnO nanoparticles were generated together under one-step hydrothermal process without secondary recombination. ZnO/Zn-3(PO4)(2)/C as anode shows the high reversible capacity of 946 mAh g(-1) after 150 cycles at 0.2 A g(-1) and the outstanding long-cycling stability of 641 mAh g(-1) after 600 cycles at 1 A g(-1). The significantly enhanced lithium storage can be ascribed to that novel pleated Zn-3(PO4)(2)/C conductive buffer accommodates the volume variation, ensures the abundant active sites and disperses ZnO nanoparticles to a certain extent during the repeated cycles. These make ZnO/Zn-3(PO4)(2)/C a potential anode for lithium ion batteries (LIBs) and provide new ideas to develop materials for other energy storage devices.
机译:我们报告了一种有效和具有成本效益的策略,可自组装可乐(ZnO / Zn-3(PO4)(2)/ C)附着到3D褶状Zn-3(PO4)(2)/ C的ZnO纳米粒子的自组装。其中,在一步一步水热过程中,无需二次复合就可以生成3D折叠的Zn-3(PO4)(2)/ C导电缓冲液和ZnO纳米颗粒。 ZnO / Zn-3(PO4)(2)/ C作为阳极在0.2 A g(-1)下经过150次循环后显示出946 mAh g(-1)的高可逆容量和641 mAh g的出色长循环稳定性(-1)在1 A g(-1)下循环600次后。锂存储的显着提高可归因于新型褶状Zn-3(PO4)(2)/ C导电缓冲液可适应体积变化,确保丰富的活性位点并在重复循环中将ZnO纳米颗粒分散到一定程度。这些使ZnO / Zn-3(PO4)(2)/ C成为锂离子电池(LIB)的潜在阳极,并为开发用于其他储能设备的材料提供了新思路。

著录项

  • 来源
    《Applied Surface Science》 |2020年第1期|145288.1-145288.9|共9页
  • 作者单位

    South China Normal Univ Guangdong Prov Engn Technol Res Ctr Low Carbon & Inst Semicond Sci & Technol Guangzhou 510631 Peoples R China;

    GU South China Inst Software Engn Guangzhou 510990 Peoples R China;

    South China Normal Univ Guangdong Prov Engn Technol Res Ctr Low Carbon & Inst Semicond Sci & Technol Guangzhou 510631 Peoples R China|South China Normal Univ Inst Sci & Technol Innovat Qingyuan 511517 Peoples R China|SCNU Qingyuan Inst Sci & Technol Innovat Co Ltd Qingyuan 511517 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Lithium-ion batteries; ZnO-based electrodes; Cola; Zn-3(PO4)(2)/C buffer; Three-dimensional;

    机译:锂离子电池;ZnO基电极;可乐;Zn-3(PO4)(2)/ C缓冲液;三维;

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