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3D flower-like Ag/Bi_5O_7I embedded on an acrylate fluoroboron polymer as a multifunctional assembly film for ultrastable plasmon-enhanced photocatalysis and antibiosis

机译:3D嵌入丙烯酸酯氟离子聚合物上的3D花样AG / Bi_5O_7i作为多功能组装膜,用于过度的等离子体增强的光催化和抗体

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摘要

Flower-like Bi5O7 I microspheres modified with Ag nanoparticles are prepared, exhibiting excellent surface plasmon resonance. Bi5O7 I/Ag/acrylate fluoroboron polymer (AFBP) ternary assembly films are also fabricated using Bi5O7 I/Ag composites uniformly distributed in acrylate fluorobomn polymer. The structure and photocatalytic properties of Bi5O7 I/Ag are characterized. Characterization results indicate that Bi5O7 I/Ag has a large specific surface area, a low band gap, and excellent visible light response. To evaluate the properties of the Bi5O7 I/Ag/AFBP ternary assembly film, laboratory diatom assays and antibacterial activity are tested. The results show excellent diatom anti-settlement performance and high antibacterial rates of 99.63% for Escherichia coli and 99.92% for Staphylococcus aureus. Photocatalytic degradation of 2,4,6-trichlomphenol by visible-light irradiation for 150 min shows a removal rate of 95%, which is attributed to charge efficiency separation. Simultaneously, the photodegradation pathway and TOC of 2,4,6-trichlorophenol are analyzed. Thus, this study shows the significance of assembly film for potential marine applications in the future.
机译:制备用Ag纳米颗粒改性的花样的Bi5O7 I微球,表现出优异的表面等离子体共振。使用均匀分布在丙烯酸酯氟能源聚合物中的Bi5O7 I / Ag复合材料,也制造Bi5O7 I / Ag /丙烯酸氟聚合物(AFBP)三元组装膜。 Bi5O7 I / Ag的结构和光催化性质的特征在于。表征结果表明Bi5O7 I / Ag具有大的比表面积,低带隙和优异的可见光响应。为了评估BI5O7 I / AG / AFBP三元组装膜的性质,测试实验室硅藻法和抗菌活性。结果表明,对于大肠杆菌的大肠杆菌,优异的硅藻抗沉降性能和高抗菌率为99.63%,金黄色葡萄球菌的99.92%。光催化剂通过可见光照射150分钟的2,4,6- richlomphenol的光催化降解显示出95%的去除率,这归因于充电效率分离。同时,分析了光降解途径和2,4,6-三氯苯酚的TOC。因此,本研究表明了将来潜在海洋应用的组装膜的重要性。

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  • 来源
    《Applied Surface Science》 |2021年第15期|150305.1-150305.8|共8页
  • 作者单位

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China|HIT Hainan Mil Civilian Integrat Innovat Res Inst Haikou 572427 Hainan Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China|HIT Hainan Mil Civilian Integrat Innovat Res Inst Haikou 572427 Hainan Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China;

    Harbin Engn Univ Coll Mat Sci & Chem Engn Key Lab Superlight Mat & Surface Technol Minist Educ Harbin 150001 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Bi5O7I; Ag nanoparticle; Acrylate fluoroboron polymer; Photocatalysis; Multi-function;

    机译:Bi5O7i;Ag纳米粒子;丙烯酸酯氟离子聚合物;光催化;多功能;

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