Kinetics of Oxidation of DL-Tartaric Acid by Potassium Permanganate in Aqueuos and Aqueous Micellar Media

Mohammed Hassan; Nabil A. Alhemiary; Abdu S. Albadani

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Kinetics of Oxidation of DL-Tartaric Acid by Potassium Permanganate in Aqueuos and Aqueous Micellar Media

机译：高锰酸钾在水和胶束水介质中氧化DL-酒石酸的动力学

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摘要

The kinetics of oxidation of DL-tartaric acid (TA) by potassium permanganate in acetic acid medium in the presence and absence of TX-100 (non-ionic surfactant) was investigated. At early stages, the reaction was found to be first order with respect to both permanganate and TA. The presence of TX-100 was found to catalyse the reaction and this effect was interpreted successfully in terms of pseudo-phase model. Activation parameters of the reaction in the presence/absence of TX-100 were obtained. A suitable mechanism, which agreed with the experimental findings was suggested.

机译：研究了在存在和不存在TX-100（非离子表面活性剂）的情况下，乙酸介质中高锰酸钾对DL-酒石酸（TA）的氧化动力学。在早期阶段，发现对于高锰酸盐和TA而言，该反应均为一级反应。发现TX-100的存在可以催化反应，并且可以用伪相模型成功地解释了这种效应。获得在有或没有TX-100的情况下反应的活化参数。提出了一种与实验结果相符的合适机理。

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来源
《Arabian Journal for Science and Engineering》 |2012年第5期|p.1263-1270|共8页
作者
Mohammed Hassan; Nabil A. Alhemiary; Abdu S. Albadani;
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作者单位

Chemistry Department, Faculty of Science,Ibb University, P. O. Box 7027, Ibb, Yemen;

Chemistry Department, Faculty of Science,Ibb University, P. O. Box 7027, Ibb, Yemen;

Chemistry Department, Faculty of Science,Ibb University, P. O. Box 7027, Ibb, Yemen;

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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种 eng
中图分类
关键词
oxidation; tartaric acid; micellar catalysis; potassium permanganate; TX-100;

机译：氧化酒石酸;胶束催化;高锰酸钾;TX-100;

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Kinetics of Oxidation of DL-Tartaric Acid by Potassium Permanganate in Aqueuos and Aqueous Micellar Media

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