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Taguchi Optimization Method for Nickel Removal from Aqueous Solutions Using Non‑living Pleurotus mutilus

机译:Taguchi优化方法的无生命平菇去除水溶液中的镍

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The main factors conditioning nickel biosorption by non-living fungal biomass of Pleurotus mutilus were studied by the means of two experimental approaches. The surface of fungal biomass was characterized by pH(ZPC) determination, Boehm titration and FTIR spectroscopy. The results demonstrated that the pH(ZPC) is found to be at pH = 7.94, and the number of acidic sites (4.33 meq g(-1)) is higher than the number of basic sites (0.58 meq g(-1)). Without the chemical precipitation of Ni(OH)(2), the one variable at time (OVAT) approach illustrates at its equilibrium time equal to 79 min, that the maximum nickel biosorption was achieved at pH 8 and optimal concentration of 488 mg L-1. However, the particle size does not affect nickel biosorption. The comparison of the optimal conditions obtained from OVAT and Taguchi methods shows comparable values of pH and equilibrium time, while differences in Ni(II) concentration and particle size were observed. Furthermore, the combination of the four factors at their optimum level improves the biosorption capacity compared to OVAT method (enhancement of 36.23%). The Taguchi method revealed that the contribution of the controlled factors on Ni(II) biosorption followed the following order: Ni(II) (76.98%) > pH (18.16%) > time (3.20%) > particle size (1.66%). The combination of the variation factors could enhance the biosorption capacities of Pleurotus mutilus biomass for use in practical applications.
机译:通过两种实验方法研究了影响侧耳无生命真菌生物量镍吸收的主要因素。通过pH(ZPC)测定,Boehm滴定和FTIR光谱对真菌生物量的表面进行表征。结果表明,pH(ZPC)位于pH = 7.94,并且酸性位点的数量(4.33 meq g(-1))比碱性位点的数量(0.58 meq g(-1))高。 。在没有化学沉淀Ni(OH)(2)的情况下,一个时间变量(OVAT)表示在其平衡时间等于79分钟时,在pH 8和488 mg L-的最佳浓度下实现了最大的镍生物吸附。 1。但是,粒径不影响镍的生物吸附。通过OVAT和Taguchi方法获得的最佳条件的比较显示出可比较的pH值和平衡时间,同时观察到了Ni(II)浓度和粒径的差异。此外,与OVAT方法相比,四种因子在最佳水平的组合提高了生物吸附能力(提高了36.23%)。 Taguchi方法揭示了控制因素对Ni(II)生物吸附的贡献顺序如下:Ni(II)(76.98%)> pH(18.16%)>时间(3.20%)>粒径(1.66%)。变异因子的组合可增强侧耳侧耳生物质在实际应用中的生物吸附能力。

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